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IMPROVE - Interagency Monitoring of Protected Visual Environments
RHR - Regional Haze Rule
The IMPROVE RHR Aerosol Program contains a version of the IMPROVE Aerosol data
with major aerosol species, additional substituted daily data values, as well as data aggregations.
Detailed descriptions of the data substitution and aggregation algorithms can be found in the RHR Guidance
Documents. General descriptions are provided below. Important
differences between the IMPROVE RHR Aerosol data and the IMPROVE Aerosol data on
VIEWS are that the RHR data contain substituted values and that measured
particle nitrate values are used in all calculations, whereas in the IMPROVE
aerosol data ammonium nitrate values have been replaced with a constant value
prior to 6/1996. Links to
RHR related data on VIEWS and IMPROVE web sites:
Raw IMPROVE data:
RHR program data are calculated from raw
IMPROVE data with the following native flags: "NM", "LF", "RF", "AA", "AP",
"SW", "SP", "NR","CG". These flags can be found in the Flag1 column of the raw
IMPROVE aerosol data.
Parameters:
The RHR dataset includes only major parameters, generally those required to
calculate visibility metrics such as aerosol extinction, deciview, and standard
visual range.
|
Parameter |
Name |
Algorithm |
Description |
| MF |
PM2.5: mass |
Measured quantity |
Gravimetric measurement of aerosol fine mass (PM2.5) |
| MT |
PM10: Mass |
Measured quantity |
Gravimetric measurement of aerosol total mass (PM10) |
| aerosol_bext |
Aerosol extinction |
ammSO4f_bext + ammNO3f_bext + OMCf_bext + ECf_bext + SOILf_bext +
CM_bext |
Sum of major aerosol species mass extinction |
|
ammNO3f |
Ammonium nitrate |
1.29*NO3f |
Ammonium nitrate from nitrate ion |
|
ammNO3f_bext |
Ammonium nitrate extinction |
3*fRH*ammNO3f |
Use mass extinction efficiency of 3m2/g for ammonium nitrate and fRH |
|
ammSO4f |
Ammonium sulfate |
4.125*Sf |
Ammonium sulfate from sulfur element |
|
ammSO4f_bext |
Ammonium sulfate extinction |
3*fRH*ammSO4f |
Use mass extinction efficiency of 3m2/g for ammonium sulfate and fRH |
|
CM |
PM2.5-10: mass |
MT-MF |
Fine mass (PM2.5) subtracted from PM10 |
| CM_bext |
Coarse mass extinction |
0.6*CM |
Use mass extinction efficiency of 0.6 m2/g for coarse mass |
| dv |
Deciview |
10*ln((aerosol_bext+10)/10) |
Perception based visibility metric |
| ECf |
Carbon: total elemental |
E1+E2+E3-OP |
Sum of elemental carbon fractions from TOR - OP |
| ECf_bext |
Elemental carbon extinction |
10*ECf |
Use mass extinction efficiency of 10m2/g for elemental carbon |
| F_CM_bext |
Coarse mass extinction
fraction |
100*CM_bext/aerosol_bext |
Contribution of coarse mass extinction to aerosol extinction |
| F_EC |
Elemental carbon fraction |
100*ECf/RCFM |
Contribution of fine elemental carbon to reconstructed fine mass |
| F_EC_bext |
Elemental carbon extinction fraction |
100*ECf_bext/aerosol_bext |
Contribution of fine elemental carbon extinction to aerosol
extinction |
| F_NO3 |
Nitrate fraction |
100*ammNO3f/RCFM |
Contribution of fine ammonium nitrate to reconstructed fine mass |
| F_NO3_bext |
Nitrate extinction fraction |
100*ammNO3f_bext/aerosol_bext |
Contribution of fine ammonium nitrate extinction to aerosol
extinction |
| F_OMC |
Organic carbon mass fraction |
100*OMCf/RCFM |
Contribution of fine organic mass to reconstructed fine mass |
| F_OMC_bext |
Organic carbon mass extinction fraction |
100*OMCf_bext/aerosol_bext |
Contribution of fine organic mass extinction to aerosol extinction |
| F_SO4 |
Sulfate fraction |
100*ammSO4f/RCFM |
Contribution of fine ammonium sulfate to reconstructed fine mass |
| F_SO4_bext |
Sulfate extinction fraction |
100*ammSO4f_bext/aerosol_bext |
Contribution of fine ammonium sulfate extinction to aerosol
extinction |
| F_SOIL |
Soil |
100*SOILf/RCFM |
Contribution of fine soil to reconstructed fine mass |
| F_SOIL_bext |
Soil extinction fraction |
100*SOILf_bext/aerosol_bext |
Contribution of fine soil extinction to aerosol extinction |
| fRHgrid |
Relative humidity factor |
gridded value |
Gridded value |
| OMCf |
Organic mass by carbon |
1.4*(O1+O2+O3+O4+OP) |
Organic carbon mass from OC |
| OMCf_bext |
Organic carbon extinction |
4*1.4*OCf |
Use mass extinction efficiency of 4 m2/g for organic carbon |
| RCFM |
Reconstructed fine mass |
ammSO4f + ammNO3f + ECf + OMCf + SOILf |
Fine mass reconstructed from major component species concentrations |
| RCTM |
Reconstructed total mass |
ammSO4f + ammNO3f + ECf + OMCf + SOILf + CM |
Sum of major fine and coarse aerosol mass concentrations |
| SOILf |
Fine Soil |
2.2*Al+2.49*Si+1.63*Ca+2.42*Fe+1.94*Ti |
Sum of common oxides of soil elements |
| SOILf_bext |
Fine soil extinction |
1*SOILf |
Use mass extinction efficiency of 1m2/g for fine soil |
| SVR |
Standard visual range |
3910/(aerosol_bext+10) |
Standard visual range in kilometers |
Metadata Flags:
|
Status Flag: |
|
Definition: |
| |
|
|
|
V2 |
|
Valid estimated value |
|
M1 |
|
Missing sample |
| VIEWS Flag: |
Description: |
Detailed Description: |
|
Flag1 |
not used |
|
|
Flag2 |
Number of years |
Applies to multi-year aggregations, such as 3-year and 5-year
rolling averages. The number of annual averages used to
form the multi-year mean. |
|
Flag3 |
Number of daily values |
Applies to single-year aggregations. The number of
daily values in the annual mean. |
|
Flag4 |
Number of substituted values |
Applies to daily values. The number of substituted
values. |
|
Flag5 |
aerosol extinction group |
Applies to daily values. |
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|
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Note: For the IRHR program, Flag 5 can have a value of
10, 30,
50, 70, 90, or #. If a daily value has a Native Flag 5 value of
90
(indicating a group 90 value), then this value is one of the RHR
prescribed Worst 20% visibility days. If the flag 5 is #,
then the year had insufficient data to form aerosol bext groups
according the the RHR guidelines and no group values are assigned for
that year.
Substituted Values:
In order to calculate chemical or 'aerosol
extinction' a given daily sample from an IMPROVE aerosol monitoring location
must have reported values for the parameters ammSO4f (ammonium sulfate), ammNO3f
(ammonium nitrate), OMCf (organic carbon mass), ECf (elemental carbon) SOILf
(soil), and CM (coarse mass). If any of these six parameters are missing
the Guidance specifies procedures to substitute the missing value. Details
of the substitution methodology and criteria are given in Section 2 of the Tracking Progress
Guidance document. In the VIEWS database any of the six aforementioned
parameters measured on a daily basis and having a Flag4 value > 0 indicates a patched value. Daily reconstructed parameters, such as RCFM
or aerosol extinction, can containing one or more substituted value have Flag4
values indicating the total number of patched values included in the
reconstructed parameter.
Data Aggregations:
|
Code |
|
Name: |
|
Definition: |
|
Criteria: |
|
|
G10 |
|
Group 10 |
|
Best 20% aerosol extinction sampling days |
|
No more than 10 consecutive missing sampling days in a year |
|
|
G50 |
|
Group 50 |
|
Mid 20% aerosol extinction sampling days |
|
" " |
|
|
G90 |
|
Group 90 |
|
Worst 20% aerosol extinction sampling days |
|
" " |
|
|
Q1 |
|
1st Quarter |
|
January, February, March Mean |
|
At least 14 valid sampling days per quarter |
|
|
Q2 |
|
2nd Quarter |
|
April, May, June Mean |
|
" " |
|
|
Q3 |
|
3rd Quarter |
|
July, August, September Mean |
|
" " |
|
|
Q4 |
|
4th Quarter |
|
October, November, December Mean |
|
" " |
|
|
1YR |
|
1-Year Mean |
|
1 year (Annual) average |
|
All four quarters must be present |
|
|
3YR |
|
3-Year Mean |
|
3 year rolling average |
|
At least 2 valid annual means in 3-year window. Date given
is the midpoint year for the averaging window |
|
|
5YR |
|
5-Year Mean |
|
5 year rolling average |
|
At least 3 valid annual means in 5-year window. Date given
is the midpoint year for the averaging window |
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- Data aggregations are comprised of
samples collected at one monitoring site over the course of more
than one sampling day.
- Aggregated data are not currently
available from the Query Wizard. These data can currently be
obtained from text files
in the Annual Summary Summary Data section or viewed in tabular and graphical format
from the various Annual Summary sections.
- All aggregated
visibility metrics in VIEWS are derived by first calculating the daily metric
(such as daily deciview or daily SVR) then averaging the daily
metrics to obtain the aggregated value. For example, the average deciview
value on the Worst 20% sampling days is calculated by taking the mean of the
daily Worst 20% deciview values. Because the decivew and SVR algorithms
are not commutative their aggregated values in VIEWS cannot be reproduced
directly from the mean aerosol extinction value for the same data
aggregation. That is, the the mean deciview value for the Worst 20%
sampling days is not necessarily equal to the the mean extinction value on the
worst 20% days converted to deciview.
Important Notice for IMPROVE RHR data:
Over the years the IMPROVE program has undergone a
number of sampling and filter analysis changes to
reduce biases and uncertainty and improve measurement sensitivities. These
changes are documented in
the quality control section of the IMPROVE website:
http://vista.cira.colostate.edu/improve/Data/QA_QC/qa_qc_Branch.htm
Two significant changes which can influence any trend work involved the fine
sulfur mass and nitrate
ion measurements. The sulfur measurement from the Module A Teflon filter can be
underestimated by over
a factor of 2. This bias occurred at only some Eastern US sites primarily during
the summers of 1992-95
on days with the highest sulfur loadings coinciding with high humidity. This
problem was rectified by
increasing the size of the Teflon filters at affected sites (Table 1). It is
recommended that data analysts
use the sulfate ion measurement from the Module B filter instead of the Sulfur
mass measurement from
module A for time periods before the Teflon filter size was increased at the
sites listed below (Table 1).
In the IMPROVE RHR data set this substitution has been made for all parameters
that include ammonium sulfate
in their calculation. In the IMPROVE RHR dataset, this substitution was
not made at sites with no evidence of
sulfur underestimation.
Table 1. Monitoring sites and dates when the Teflon filter was increased from
2.2 sq. cm to 3.5 sq. cm :
Apr 19, 1995 - DOSO1,GRSM1,SHEN1,JEFF1
Apr 22, 1995 - SAGO1
Apr 26, 1995 - ACAD1,LYBR1,SHRO1,MACA1
May 03, 1995 - SIPS1,UPBU1
May 10, 1995 - BRIG1
May 27, 1998 - SEQU1
Jun 03, 1998 - PUSO1
Jul 29, 1998 - MOOS1
Aug 04, 1998 - CHAS1,OKEF1,ROMA1,EVER1
Apr 17, 2001 - CACR1
Apr 25, 2001 - HEGL1,GUMO1,BIBE1
May 16, 2001 - WIMO1
Note: there is no evidence of S underestimation at BIBE1, GUMO1, MOOS1, SAGO1 and SEQU1.
For detailed information on the bias and recommendations see the QA/QC issues
page on the IMPROVE website at:
http://vista.cira.colostate.edu/improve/Data/QA_QC/issues.htm
A temporal bias also exist in the IMPROVE nitrate ion data. For a period after
6/1996 The nitrate data have smaller
concentrations and variability. This is most pronounced in the Eastern US and
along the West Coast. The
change in the nitrate data coincides with the addition of glycerin to the
denuders for the Module B sampler.
However, a causality has not yet been established and is currently being
studied. In the IMPROVE RHR dataset the
the measured particle nitrate value is used to calculate ammonium nitrate.
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