IMPROVE - Interagency Monitoring of Protected Visual Environments

RHR -  Regional Haze Rule

The IMPROVE RHR Aerosol Program contains a version of the IMPROVE Aerosol data with major aerosol species, additional substituted daily data values, as well as data aggregations.  Detailed descriptions of the data substitution and aggregation algorithms can be found in the RHR Guidance Documents.  General descriptions are provided below.  Important differences between the IMPROVE RHR Aerosol data and the IMPROVE Aerosol data on VIEWS are that the RHR data contain substituted values and that measured particle nitrate values are used in all calculations, whereas in the IMPROVE aerosol data ammonium nitrate values have been replaced with a constant value prior to 6/1996.

Links to RHR related data on VIEWS and IMPROVE web sites:

Raw IMPROVE data:

RHR program data are calculated from raw IMPROVE data with the following native flags: "NM", "LF", "RF", "AA", "AP", "SW", "SP", "NR","CG".  These flags can be found in the Flag1 column of the raw IMPROVE aerosol data.

Parameters:

The RHR dataset includes only major parameters, generally those required to calculate visibility metrics such as aerosol extinction, deciview, and standard visual range.

Parameter Name Algorithm Description
MF PM2.5: mass Measured quantity Gravimetric measurement of aerosol fine mass (PM2.5)
MT PM10: Mass Measured quantity Gravimetric measurement of aerosol total mass (PM10)
aerosol_bext Aerosol extinction ammSO4f_bext + ammNO3f_bext + OMCf_bext + ECf_bext + SOILf_bext + CM_bext Sum of major aerosol species mass extinction
ammNO3f Ammonium nitrate 1.29*NO3f Ammonium nitrate from nitrate ion
ammNO3f_bext Ammonium nitrate extinction 3*fRH*ammNO3f Use mass extinction efficiency of 3m2/g for ammonium nitrate and fRH
ammSO4f Ammonium sulfate 4.125*Sf Ammonium sulfate from sulfur element
ammSO4f_bext Ammonium sulfate extinction 3*fRH*ammSO4f Use mass extinction efficiency of 3m2/g for ammonium sulfate and fRH
CM PM2.5-10: mass MT-MF Fine mass (PM2.5) subtracted from PM10
CM_bext Coarse mass extinction 0.6*CM Use mass extinction efficiency of 0.6 m2/g for coarse mass
dv Deciview 10*ln((aerosol_bext+10)/10) Perception based visibility metric
ECf Carbon: total elemental E1+E2+E3-OP Sum of elemental carbon fractions from TOR - OP
ECf_bext Elemental carbon extinction 10*ECf Use mass extinction efficiency of 10m2/g for elemental carbon
F_CM_bext Coarse mass extinction fraction 100*CM_bext/aerosol_bext Contribution of coarse mass extinction to aerosol extinction
F_EC Elemental carbon fraction 100*ECf/RCFM Contribution of fine elemental carbon to reconstructed fine mass
F_EC_bext Elemental carbon extinction fraction 100*ECf_bext/aerosol_bext Contribution of fine elemental carbon extinction to aerosol extinction
F_NO3 Nitrate fraction 100*ammNO3f/RCFM Contribution of fine ammonium nitrate to reconstructed fine mass
F_NO3_bext Nitrate extinction fraction 100*ammNO3f_bext/aerosol_bext Contribution of fine ammonium nitrate extinction to aerosol extinction
F_OMC Organic carbon mass fraction 100*OMCf/RCFM Contribution of fine organic mass to reconstructed fine mass
F_OMC_bext Organic carbon mass extinction fraction 100*OMCf_bext/aerosol_bext Contribution of fine organic mass extinction to aerosol extinction
F_SO4 Sulfate fraction 100*ammSO4f/RCFM Contribution of fine ammonium sulfate to reconstructed fine mass
F_SO4_bext Sulfate extinction fraction 100*ammSO4f_bext/aerosol_bext Contribution of fine ammonium sulfate extinction to aerosol extinction
F_SOIL Soil 100*SOILf/RCFM Contribution of fine soil to reconstructed fine mass
F_SOIL_bext Soil extinction fraction 100*SOILf_bext/aerosol_bext Contribution of fine soil extinction to aerosol extinction
fRHgrid Relative humidity factor gridded value Gridded value
OMCf  Organic mass by carbon 1.4*(O1+O2+O3+O4+OP) Organic carbon mass from OC
OMCf_bext Organic carbon extinction 4*1.4*OCf Use mass extinction efficiency of 4 m2/g for organic carbon
RCFM Reconstructed fine mass ammSO4f + ammNO3f + ECf + OMCf + SOILf Fine mass reconstructed from major component species concentrations
RCTM Reconstructed total mass ammSO4f + ammNO3f + ECf + OMCf + SOILf + CM Sum of major fine and coarse aerosol mass concentrations
SOILf  Fine Soil 2.2*Al+2.49*Si+1.63*Ca+2.42*Fe+1.94*Ti Sum of common oxides of soil elements
SOILf_bext Fine soil extinction 1*SOILf Use mass extinction efficiency of 1m2/g for fine soil
SVR Standard visual range 3910/(aerosol_bext+10) Standard visual range in kilometers

Metadata Flags:

Status Flag:   Definition:
     
V2   Valid estimated value 
M1   Missing sample

VIEWS Flag: Description: Detailed Description:
Flag1 not used  
Flag2 Number of years Applies to multi-year aggregations, such as 3-year and 5-year rolling averages.  The number of annual averages used to form the multi-year mean.
Flag3 Number of daily values Applies to single-year aggregations.  The number of daily values in the annual mean.
Flag4 Number of substituted values Applies to daily values.  The number of substituted values.
Flag5 aerosol extinction group Applies to daily values. 
     

Note: For the IRHR program, Flag 5 can have a value of 10, 30, 50, 70, 90, or #.  If a daily value has a Native Flag 5 value of 90 (indicating a group 90 value), then this value is one of the RHR prescribed Worst 20% visibility days.   If the flag 5 is #, then the year had insufficient data to form aerosol bext groups according the the RHR guidelines and no group values are assigned for that year.

Substituted Values:

In order to calculate chemical or 'aerosol extinction' a given daily sample from an IMPROVE aerosol monitoring location must have reported values for the parameters ammSO4f (ammonium sulfate), ammNO3f (ammonium nitrate), OMCf (organic carbon mass), ECf (elemental carbon) SOILf (soil), and CM (coarse mass).  If any of these six parameters are missing the Guidance specifies procedures to substitute the missing value.  Details of the substitution methodology and criteria are given in Section 2 of the Tracking Progress Guidance document.  In the VIEWS database any of the six aforementioned parameters measured on a daily basis and having a Flag4 value > 0 indicates a patched value.  Daily reconstructed parameters, such as RCFM or aerosol extinction, can containing one or more substituted value have Flag4 values indicating the total number of patched values included in the reconstructed parameter.

Data Aggregations:

Code   Name:    Definition:   Criteria:  
G10   Group 10   Best 20% aerosol extinction sampling days   No more than 10 consecutive missing sampling days in a year  
G50   Group 50   Mid 20% aerosol extinction sampling days                                " "  
G90   Group 90   Worst 20% aerosol extinction sampling days                                " "  
Q1   1st Quarter   January, February, March Mean   At least 14 valid sampling days per quarter  
Q2   2nd Quarter   April, May, June Mean                                " "  
Q3   3rd Quarter   July, August, September Mean                                " "  
Q4   4th Quarter   October, November, December Mean                                " "  
1YR   1-Year Mean   1 year (Annual) average   All four quarters must be present  
3YR   3-Year Mean   3 year rolling average   At least 2 valid annual means in 3-year window.  Date given is the midpoint year for the averaging window  
5YR   5-Year Mean   5 year rolling average   At least 3 valid annual means in 5-year window.  Date given is the midpoint year for the averaging window  
  1. Data aggregations are comprised of samples collected at one monitoring site over the course of more than one sampling day.
  2. Aggregated data are not currently available from the Query Wizard.  These data can currently be obtained from text files in the Annual Summary Summary Data section or viewed in tabular and graphical format from the various Annual Summary sections.
  3. All aggregated visibility metrics in VIEWS are derived by first calculating the daily metric (such as daily deciview or daily SVR) then averaging the daily metrics to obtain the aggregated value.  For example, the average deciview value on the Worst 20% sampling days is calculated by taking the mean of the daily Worst 20% deciview values.  Because the decivew and SVR algorithms are not commutative their aggregated values in VIEWS cannot be reproduced directly from the mean aerosol extinction value for the same data aggregation.  That is, the the mean deciview value for the Worst 20% sampling days is not necessarily equal to the the mean extinction value on the worst 20% days converted to deciview.

Important Notice for IMPROVE RHR data:

Over the years the IMPROVE program has undergone a number of sampling and filter analysis changes to
reduce biases and uncertainty and improve measurement sensitivities. These changes are documented in
the quality control section of the IMPROVE website:

http://vista.cira.colostate.edu/improve/Data/QA_QC/qa_qc_Branch.htm

Two significant changes which can influence any trend work involved the fine sulfur mass and nitrate
ion measurements. The sulfur measurement from the Module A Teflon filter can be underestimated by over
a factor of 2. This bias occurred at only some Eastern US sites primarily during the summers of 1992-95
on days with the highest sulfur loadings coinciding with high humidity. This problem was rectified by
increasing the size of the Teflon filters at affected sites (Table 1). It is recommended that data analysts
use the sulfate ion measurement from the Module B filter instead of the Sulfur mass measurement from
module A for time periods before the Teflon filter size was increased at the sites listed below (Table 1). 
In the IMPROVE RHR data set this substitution has been made for all parameters that include ammonium sulfate
in their calculation.  In the IMPROVE RHR dataset, this substitution was not made at sites with no evidence of
sulfur underestimation.

Table 1. Monitoring sites and dates when the Teflon filter was increased from 2.2 sq. cm to 3.5 sq. cm :

Apr 19, 1995 - DOSO1,GRSM1,SHEN1,JEFF1
Apr 22, 1995 - SAGO1
Apr 26, 1995 - ACAD1,LYBR1,SHRO1,MACA1
May 03, 1995 - SIPS1,UPBU1
May 10, 1995 - BRIG1
May 27, 1998 - SEQU1
Jun 03, 1998 - PUSO1
Jul 29, 1998 - MOOS1
Aug 04, 1998 - CHAS1,OKEF1,ROMA1,EVER1
Apr 17, 2001 - CACR1
Apr 25, 2001 - HEGL1,GUMO1,BIBE1
May 16, 2001 - WIMO1

Note: there is no evidence of S underestimation at BIBE1, GUMO1, MOOS1, SAGO1 and SEQU1.

For detailed information on the bias and recommendations see the QA/QC issues page on the IMPROVE website at:

http://vista.cira.colostate.edu/improve/Data/QA_QC/issues.htm

A temporal bias also exist in the IMPROVE nitrate ion data. For a period after  6/1996 The nitrate data have smaller
concentrations and variability.  This is most pronounced in the Eastern US and along the West Coast. The
change in the nitrate data coincides with the addition of glycerin to the denuders for the Module B sampler.
However, a causality has not yet been established and is currently being studied.   In the IMPROVE RHR dataset the
the measured particle nitrate value is used to calculate ammonium nitrate.