ANNUAL TRENDS - AMBIENT MASS Annual Group 10, 50, 90 average concentrations of the total fine (PM2.5) and coarse (PM2.5-PM10) mass and major fine aerosol types. The fractional contribution of the aerosol types to the reconstructed fine aerosol mass is also provided. These data are for all IMPROVE sites with data from 1988 - 1999. These data were used to construct the long term trends aerosol trends. All calculations followed the procedures from the Draft Guidance for Tracking Progress Under the Regional Haze Rule (9/27/01). (see http://vista.cira.colostate.edu/improve/Publications/GuidanceDocs/guidancedocs.htm) A possible bias in the pre 6/1996 nitrate data and some of the eastern US particle sulfur data exists. For more information see http://vista.cira.colostate.edu/improve/Data/QA_QC/issues.htm. To minimize these biases SO4 ion data were used to replace all potentially biased sulfur data. Constant group 10, 50 and 90 ammonium nitrate value were used in all calculations, where the ammonium nitrate values were calculated from the 1997-99 data following the procedures from the Draft Guidance for Tracking Progress Under the Regional Haze Rule (9/27/01). Information about the IMPROVE monitoring sites can be obtained from: http://vista.cira.colostate.edu/improve/data/graphicViewer/metadata.asp VARIABLE DEFINITIONS AND UNITS: Group 10 = The average of the data between the 0th and 20th percentile Group 50 = The average of the data between the 40th and 60th percentile Group 90 = The average of the data between the 80th and 100th percentile TM = PM10 CM = COARSE MASS, THE DIFFERENCE OF PM10 AND PM2.5 - (micrograms/cubic meter) RCFM = RECONSTRUCTED PM2.5 - (micrograms/cubic meter) SO4 = AMMONIUM SULFATE MASS - (micrograms/cubic meter) NO3 = AMMONIUM NITRATE MASS - (micrograms/cubic meter) OMC= ORGANIC MASS - (micrograms/cubic meter) LAC = LIGHT ABSORBING CARBON MASS - (micrograms/cubic meter) SOIL = FINE SOIL MASS - (micrograms/cubic meter) THE PREFIX "F_" DENOTES THE PERCENT OF FMASS DUE TO THE INDIVIDUAL SPECIES ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 156 -------------------------------------------------- site=ACAD GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 9.10 4.08 2.14511 1.10 51.2 0.11 4.90 0.66 30.8 0.17 7.81 0.11 5.29 1991 6.79 3.80 2.42338 1.07 44.2 0.11 4.34 0.96 39.4 0.15 6.04 0.15 6.03 1992 5.37 3.06 2.02842 1.06 52.4 0.11 5.18 0.62 30.7 0.17 8.15 0.07 3.51 1993 5.99 3.11 2.19319 1.12 51.1 0.11 4.79 0.69 31.3 0.16 7.09 0.13 5.73 1994 5.73 3.22 2.04766 0.84 40.9 0.11 5.13 0.80 39.2 0.16 8.03 0.14 6.67 1995 6.20 3.76 1.96307 0.95 48.2 0.11 5.35 0.64 32.5 0.14 6.94 0.14 7.03 1996 5.06 2.96 1.76693 0.77 43.6 0.11 5.95 0.68 38.4 0.11 6.47 0.10 5.64 1997 7.54 4.53 1.95038 0.82 41.9 0.11 5.39 0.75 38.4 0.11 5.57 0.17 8.76 1998 6.06 3.27 1.96753 0.89 45.2 0.11 5.34 0.68 34.7 0.09 4.80 0.20 9.99 1999 5.92 3.51 1.67763 0.75 45.0 0.11 6.26 0.55 32.7 0.11 6.42 0.16 9.65 -------------------------------------------------- site=ACAD GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 12.13 5.74 4.69989 2.68 57.0 0.24 5.18 1.29 27.5 0.30 6.36 0.19 4.02 1991 11.93 5.41 4.94131 2.48 50.2 0.24 4.93 1.67 33.8 0.32 6.45 0.23 4.57 1992 10.00 3.75 4.74707 2.50 52.6 0.24 5.13 1.43 30.1 0.41 8.56 0.17 3.59 1993 8.83 3.93 4.42892 2.37 53.5 0.24 5.50 1.38 31.2 0.27 6.07 0.17 3.75 1994 11.90 6.08 5.02856 2.52 50.2 0.24 4.84 1.72 34.1 0.30 5.91 0.25 4.91 1995 9.58 4.97 3.90428 2.04 52.3 0.24 6.24 1.18 30.1 0.24 6.09 0.20 5.22 1996 10.03 4.89 3.76725 2.09 55.5 0.24 6.46 1.06 28.2 0.19 5.01 0.18 4.80 1997 10.50 5.03 4.41402 2.55 57.7 0.24 5.52 1.23 27.8 0.22 4.89 0.18 4.05 1998 9.82 4.55 3.75403 1.73 46.2 0.24 6.49 1.27 33.8 0.20 5.41 0.30 8.10 1999 8.15 3.61 3.60395 1.82 50.5 0.24 6.76 1.13 31.4 0.19 5.32 0.22 6.04 -------------------------------------------------- site=ACAD GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 24.33 8.65 12.4958 7.93 63.5 0.48 3.85 2.91 23.3 0.84 6.75 0.33 2.64 1991 21.15 6.33 12.8804 7.52 58.4 0.48 3.74 3.93 30.5 0.61 4.76 0.33 2.60 1992 17.65 2.75 13.7784 9.57 69.5 0.48 3.49 2.89 21.0 0.57 4.17 0.26 1.92 1993 21.35 5.98 14.2713 9.45 66.2 0.48 3.37 3.27 22.9 0.53 3.72 0.53 3.73 1994 26.92 8.29 15.9062 10.69 67.2 0.48 3.02 3.61 22.7 0.62 3.91 0.51 3.21 1995 20.04 6.99 11.2286 6.34 56.5 0.48 4.28 3.60 32.1 0.46 4.11 0.34 3.02 1996 18.52 5.45 11.0697 7.33 66.2 0.48 4.35 2.57 23.2 0.44 3.95 0.25 2.27 1997 20.39 7.17 10.3665 5.99 57.8 0.48 4.64 3.17 30.6 0.43 4.11 0.30 2.88 1998 20.79 7.82 11.1538 7.01 62.8 0.48 4.31 2.70 24.3 0.51 4.57 0.45 4.02 1999 19.54 6.06 11.1469 7.54 67.7 0.48 4.32 2.39 21.4 0.39 3.52 0.34 3.05 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 157 -------------------------------------------------- site=BADL GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 4.75 2.56 1.84076 0.56 30.2 0.14 7.38 0.65 35.4 0.07 4.06 0.42 22.9 1990 5.28 2.37 1.97794 0.60 30.4 0.14 6.87 0.74 37.3 0.10 5.16 0.40 20.3 1991 4.70 2.27 1.86145 0.61 32.5 0.14 7.30 0.67 35.8 0.09 4.93 0.36 19.5 1992 4.79 2.58 1.71649 0.62 36.4 0.14 7.91 0.59 34.6 0.07 3.97 0.29 17.2 1993 5.13 3.24 1.69127 0.65 38.3 0.14 8.03 0.56 33.4 0.06 3.73 0.28 16.5 1994 5.82 3.46 1.85630 0.66 35.5 0.14 7.32 0.60 32.1 0.11 5.80 0.36 19.3 1995 4.01 2.44 1.48421 0.49 33.3 0.14 9.15 0.53 35.8 0.08 5.08 0.25 16.6 1996 5.42 3.39 1.83019 0.73 40.0 0.14 7.42 0.61 33.1 0.09 4.73 0.27 14.8 1997 5.16 3.10 1.59261 0.55 34.6 0.14 8.53 0.60 37.4 0.07 4.39 0.24 15.1 1998 5.28 3.63 1.63272 0.58 35.8 0.14 8.32 0.54 32.9 0.08 5.02 0.29 17.9 1999 4.47 2.96 1.42747 0.49 34.3 0.14 9.52 0.44 30.5 0.09 5.98 0.28 19.7 -------------------------------------------------- site=BADL GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 11.68 7.53 3.68347 1.25 34.0 0.24 6.60 1.12 30.5 0.15 4.11 0.91 24.7 1990 10.33 4.52 3.94670 1.40 35.4 0.24 6.16 1.32 33.4 0.20 5.07 0.79 20.0 1991 9.28 5.01 3.63421 1.55 42.7 0.24 6.69 1.12 30.8 0.14 3.87 0.58 15.9 1992 10.58 6.74 3.22020 1.28 39.7 0.24 7.55 0.87 26.9 0.10 3.05 0.73 22.8 1993 7.49 4.02 3.12371 1.32 42.2 0.24 7.78 1.08 34.6 0.13 4.06 0.35 11.3 1994 9.42 5.03 3.77701 1.58 41.8 0.24 6.43 1.32 35.1 0.13 3.42 0.50 13.3 1995 6.87 2.94 3.03702 1.40 46.1 0.24 8.00 0.94 31.0 0.15 4.89 0.30 9.94 1996 9.52 5.25 3.50938 1.57 44.7 0.24 6.92 1.07 30.6 0.16 4.63 0.46 13.1 1997 9.92 5.87 3.12719 1.50 48.0 0.24 7.77 0.91 29.2 0.11 3.51 0.36 11.5 1998 7.38 3.49 3.72094 1.77 47.6 0.24 6.53 1.14 30.7 0.16 4.38 0.40 10.8 1999 8.80 5.56 2.87812 1.06 36.7 0.24 8.44 0.94 32.8 0.12 4.15 0.52 17.9 -------------------------------------------------- site=BADL GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 15.57 8.35 7.23194 3.01 41.6 1.15 15.8 1.81 25.0 0.24 3.38 1.03 14.2 1990 21.45 12.07 7.86988 2.88 36.6 1.15 14.6 2.28 29.0 0.24 2.99 1.32 16.8 1991 17.69 9.25 7.97126 3.22 40.5 1.15 14.4 2.21 27.8 0.23 2.86 1.16 14.5 1992 17.03 9.45 7.55213 3.82 50.6 1.15 15.2 1.46 19.4 0.21 2.78 0.91 12.1 1993 12.08 4.92 6.75098 3.17 46.9 1.15 17.0 1.72 25.4 0.21 3.11 0.51 7.57 1994 18.26 8.39 8.26007 2.88 34.8 1.15 13.9 3.16 38.2 0.28 3.37 0.80 9.70 1995 14.90 7.25 6.99150 2.80 40.1 1.15 16.4 2.07 29.6 0.22 3.13 0.76 10.9 1996 14.91 7.83 6.51269 3.19 49.0 1.15 17.6 1.43 21.9 0.19 2.98 0.56 8.59 1997 16.25 8.73 6.37441 2.79 43.7 1.15 18.0 1.59 25.0 0.17 2.74 0.67 10.6 1998 18.29 8.20 8.92257 3.99 44.8 1.15 12.8 2.58 28.9 0.28 3.12 0.93 10.4 1999 17.94 10.68 6.73832 2.59 38.5 1.15 17.0 1.84 27.4 0.22 3.28 0.94 13.9 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 158 -------------------------------------------------- site=BAND GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 6.23 3.78 1.95796 0.60 30.4 0.11 5.76 0.59 30.1 0.05 2.70 0.61 31.0 1993 5.09 2.52 2.03395 0.82 40.3 0.11 5.54 0.61 29.8 0.09 4.19 0.41 20.1 1994 4.91 2.73 1.87171 0.64 34.4 0.11 6.03 0.63 33.6 0.10 5.45 0.38 20.5 1995 3.97 2.48 1.53898 0.49 31.7 0.11 7.33 0.50 32.5 0.10 6.19 0.34 22.2 1996 4.07 2.41 1.47457 0.47 31.9 0.11 7.65 0.46 31.2 0.11 7.31 0.32 21.9 1997 4.50 2.44 1.66048 0.58 34.7 0.11 6.79 0.59 35.5 0.10 6.16 0.28 16.9 1998 5.07 3.20 1.80688 0.65 36.2 0.11 6.24 0.58 32.1 0.12 6.42 0.35 19.1 1999 5.10 3.00 1.86826 0.51 27.5 0.11 6.04 0.65 34.6 0.12 6.62 0.47 25.2 -------------------------------------------------- site=BAND GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 11.08 6.82 3.79595 1.07 28.2 0.20 5.38 1.22 32.1 0.16 4.33 1.14 29.9 1993 7.51 4.02 3.08367 1.00 32.4 0.20 6.63 1.20 39.0 0.19 6.02 0.49 16.0 1994 6.96 3.72 2.88717 0.97 33.7 0.20 7.08 1.03 35.7 0.19 6.49 0.49 17.0 1995 6.63 3.79 2.54106 0.86 33.9 0.20 8.04 0.81 31.9 0.19 7.58 0.47 18.5 1996 6.61 3.62 2.75133 0.93 33.6 0.20 7.43 0.99 36.0 0.16 5.68 0.47 17.2 1997 7.31 3.60 2.87703 1.15 39.9 0.20 7.10 0.94 32.5 0.15 5.32 0.44 15.2 1998 7.48 4.36 3.17053 0.99 31.2 0.20 6.44 1.28 40.5 0.21 6.49 0.49 15.4 1999 6.35 2.91 2.91027 0.97 33.2 0.20 7.02 1.05 36.2 0.17 5.75 0.52 17.8 -------------------------------------------------- site=BAND GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 15.28 8.01 6.08129 2.63 43.3 0.34 5.51 1.92 31.5 0.27 4.42 0.93 15.3 1993 11.35 5.28 5.10177 1.77 34.6 0.34 6.57 2.04 40.0 0.28 5.59 0.68 13.3 1994 11.32 5.87 4.98283 1.86 37.3 0.34 6.73 1.62 32.6 0.21 4.23 0.95 19.2 1995 10.38 5.00 5.19861 1.94 37.4 0.34 6.45 1.70 32.6 0.25 4.81 0.97 18.7 1996 14.00 8.28 5.10404 1.53 30.0 0.34 6.57 1.80 35.4 0.22 4.40 1.21 23.7 1997 12.50 6.95 4.91862 2.01 40.9 0.34 6.81 1.70 34.5 0.22 4.56 0.65 13.2 1998 12.40 6.59 6.16237 2.09 33.9 0.34 5.44 2.63 42.6 0.31 5.04 0.80 13.0 1999 12.53 6.79 5.24368 1.69 32.3 0.34 6.39 1.73 33.0 0.27 5.09 1.22 23.3 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 159 -------------------------------------------------- site=BIBE GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 8.00 4.86 2.49088 1.14 45.8 0.12 4.87 0.48 19.4 0.09 3.59 0.66 26.3 1991 7.06 4.11 2.42278 1.05 43.2 0.12 5.01 0.65 26.9 0.08 3.40 0.52 21.4 1992 7.13 5.08 1.80470 0.85 47.2 0.12 6.73 0.46 25.2 0.07 4.08 0.30 16.8 1993 5.42 3.22 2.09369 1.06 50.4 0.12 5.80 0.59 28.1 0.07 3.12 0.26 12.5 1994 6.60 3.88 2.49474 1.05 42.1 0.12 4.87 0.74 29.6 0.11 4.56 0.47 18.9 1995 6.78 4.33 2.17712 0.82 37.7 0.12 5.57 0.63 29.0 0.10 4.53 0.50 23.1 1997 5.50 2.96 1.84165 0.79 42.8 0.12 6.59 0.54 29.3 0.08 4.55 0.31 16.7 1998 7.70 4.61 2.89257 1.20 41.5 0.12 4.20 0.88 30.4 0.12 4.18 0.57 19.7 1999 8.39 5.20 2.73142 0.98 35.8 0.12 4.44 0.69 25.3 0.13 4.91 0.81 29.5 -------------------------------------------------- site=BIBE GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 14.07 8.05 4.88991 1.96 40.1 0.26 5.25 1.05 21.5 0.16 3.21 1.46 29.9 1991 13.60 8.08 4.68135 2.06 44.0 0.26 5.48 1.17 25.0 0.13 2.81 1.07 22.8 1992 10.23 5.39 4.28036 2.01 46.9 0.26 6.00 1.02 23.8 0.12 2.91 0.87 20.3 1993 12.25 6.90 4.93436 2.10 42.5 0.26 5.20 1.15 23.3 0.12 2.45 1.31 26.6 1994 15.05 8.84 5.03051 2.32 46.1 0.26 5.10 1.17 23.3 0.17 3.45 1.11 22.1 1995 11.18 6.36 4.52909 2.45 54.1 0.26 5.67 0.92 20.4 0.15 3.31 0.75 16.5 1997 11.11 6.22 4.35953 2.08 47.8 0.26 5.89 1.05 24.1 0.14 3.12 0.83 19.1 1998 15.49 9.33 5.89302 2.41 40.9 0.26 4.36 1.27 21.6 0.16 2.73 1.79 30.4 1999 18.45 10.77 6.67731 2.49 37.3 0.26 3.84 1.40 21.0 0.18 2.71 2.35 35.2 -------------------------------------------------- site=BIBE GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 20.21 10.21 7.3337 4.10 56.0 0.31 4.28 1.62 22.1 0.29 3.89 1.01 13.7 1991 24.54 14.46 8.4780 3.90 46.0 0.31 3.70 2.42 28.5 0.28 3.32 1.57 18.5 1992 19.11 10.67 7.5790 4.21 55.6 0.31 4.14 1.58 20.8 0.21 2.83 1.26 16.7 1993 17.95 8.41 8.6972 4.22 48.5 0.31 3.61 2.42 27.8 0.30 3.41 1.45 16.7 1994 19.75 9.06 9.5872 5.07 52.9 0.31 3.27 2.09 21.8 0.25 2.60 1.87 19.5 1995 23.30 12.90 9.3617 4.51 48.2 0.31 3.35 2.10 22.4 0.27 2.92 2.17 23.2 1997 19.71 8.95 9.6500 5.07 52.5 0.31 3.25 1.66 17.2 0.21 2.19 2.39 24.8 1998 26.89 11.18 13.6931 6.83 49.9 0.31 2.29 4.70 34.3 0.45 3.28 1.40 10.2 1999 35.01 21.09 12.1377 5.17 42.6 0.31 2.59 2.30 18.9 0.27 2.23 4.09 33.7 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 160 -------------------------------------------------- site=BOWA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 4.04 1.63 1.84255 0.86 46.9 0.08 4.40 0.71 38.4 0.08 4.15 0.11 6.18 1993 4.21 2.28 1.53290 0.65 42.6 0.08 5.29 0.63 41.1 0.05 3.12 0.12 7.95 1994 3.81 2.14 1.49782 0.63 41.8 0.08 5.42 0.60 39.9 0.06 3.75 0.14 9.13 1995 2.47 1.34 1.28838 0.64 49.5 0.08 6.30 0.37 28.6 0.06 4.96 0.14 10.6 1997 4.21 2.31 1.48377 0.52 35.2 0.08 5.47 0.70 47.1 0.07 4.81 0.11 7.40 -------------------------------------------------- site=BOWA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 7.94 3.03 4.13621 1.95 47.1 0.31 7.45 1.39 33.7 0.20 4.84 0.28 6.88 1993 6.62 2.82 3.36561 1.50 44.6 0.31 9.15 1.18 35.1 0.12 3.61 0.25 7.55 1994 8.67 4.11 3.70601 1.37 37.0 0.31 8.31 1.60 43.2 0.14 3.71 0.29 7.78 1995 4.94 1.93 2.83594 1.55 54.6 0.31 10.9 0.68 23.9 0.11 4.05 0.19 6.65 1997 7.98 4.13 3.15960 1.36 43.0 0.31 9.75 1.13 35.7 0.13 4.19 0.23 7.38 -------------------------------------------------- site=BOWA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 15.89 4.03 10.9745 5.77 52.6 2.00 18.3 2.49 22.7 0.34 3.08 0.38 3.43 1993 14.70 4.08 9.7448 4.48 45.9 2.00 20.6 2.61 26.8 0.30 3.12 0.35 3.58 1994 17.18 4.98 10.6227 4.14 39.0 2.00 18.9 3.51 33.1 0.39 3.64 0.58 5.48 1995 13.86 3.96 9.5627 2.89 30.2 2.00 21.0 3.90 40.8 0.40 4.16 0.37 3.88 1997 15.96 5.25 9.4188 4.32 45.9 2.00 21.3 2.29 24.3 0.33 3.52 0.48 5.05 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 161 -------------------------------------------------- site=BRCA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 3.24 1.64 1.33540 0.46 34.2 0.11 8.21 0.36 26.6 0.04 2.66 0.38 28.2 1991 3.58 1.75 1.32098 0.39 29.8 0.11 8.30 0.48 36.1 0.03 2.45 0.31 23.3 1992 3.79 1.92 1.45807 0.60 41.0 0.11 7.52 0.45 31.0 0.06 4.36 0.24 16.2 1993 3.42 1.98 1.17393 0.41 34.7 0.11 9.34 0.39 33.1 0.04 3.12 0.23 19.7 1994 3.39 1.79 1.05030 0.37 34.8 0.11 10.4 0.30 28.6 0.04 4.21 0.23 22.0 1995 2.41 1.30 1.03326 0.33 31.5 0.11 10.6 0.31 30.1 0.07 6.45 0.22 21.3 1996 2.49 1.43 0.87873 0.26 30.2 0.11 12.5 0.28 31.6 0.06 7.25 0.16 18.5 1997 2.82 1.30 1.14018 0.38 33.2 0.11 9.62 0.37 32.3 0.06 5.64 0.22 19.3 1998 2.81 1.56 1.08643 0.32 29.6 0.11 10.1 0.37 33.9 0.06 5.28 0.23 21.1 1999 2.72 1.23 1.16623 0.38 32.3 0.11 9.40 0.42 35.7 0.05 4.33 0.21 18.3 -------------------------------------------------- site=BRCA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 6.68 2.52 3.02826 0.95 31.5 0.24 8.03 0.93 30.7 0.13 4.23 0.77 25.6 1991 8.12 5.08 2.76776 0.83 29.8 0.24 8.78 0.82 29.5 0.11 3.82 0.78 28.1 1992 6.54 3.65 2.39709 1.00 41.7 0.24 10.1 0.65 27.1 0.09 3.62 0.42 17.5 1993 6.48 3.51 2.44666 0.86 35.3 0.24 9.93 0.72 29.4 0.09 3.61 0.53 21.8 1994 6.89 3.65 2.42778 0.99 40.9 0.24 10.0 0.71 29.1 0.09 3.85 0.39 16.1 1995 5.12 2.56 2.63072 0.88 33.4 0.24 9.24 0.79 30.0 0.14 5.26 0.58 22.1 1996 6.37 3.02 2.83615 0.93 32.6 0.24 8.57 0.92 32.4 0.15 5.38 0.60 21.0 1997 4.96 2.55 2.17369 0.74 34.3 0.24 11.2 0.68 31.1 0.12 5.51 0.39 18.0 1998 5.38 3.09 2.14116 0.77 35.8 0.24 11.4 0.69 32.4 0.10 4.45 0.34 16.0 1999 6.45 3.72 2.35133 0.83 35.4 0.24 10.3 0.78 33.1 0.11 4.52 0.39 16.6 -------------------------------------------------- site=BRCA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 9.45 5.10 3.72520 1.51 40.6 0.39 10.4 1.11 29.9 0.19 5.10 0.52 14.0 1991 14.16 9.73 3.99001 1.36 34.0 0.39 9.71 1.04 26.0 0.16 3.93 1.05 26.4 1992 10.76 6.08 4.11738 1.53 37.1 0.39 9.41 1.32 32.2 0.20 4.76 0.68 16.6 1993 10.32 5.08 4.51445 1.39 30.8 0.39 8.58 1.88 41.7 0.23 5.02 0.63 13.9 1994 11.06 5.89 4.36054 1.53 35.1 0.39 8.89 1.36 31.2 0.19 4.45 0.89 20.4 1995 8.40 3.87 4.12456 1.74 42.2 0.39 9.39 1.08 26.2 0.17 4.14 0.75 18.1 1996 12.24 5.97 5.70186 1.32 23.2 0.39 6.80 2.60 45.5 0.40 7.09 0.99 17.4 1997 10.68 4.74 5.29386 1.44 27.2 0.39 7.32 2.38 45.0 0.26 4.90 0.83 15.6 1998 8.84 4.00 4.93046 1.63 33.0 0.39 7.86 1.73 35.2 0.18 3.61 1.01 20.4 1999 11.24 6.32 4.64712 1.13 24.2 0.39 8.34 2.05 44.2 0.21 4.42 0.87 18.8 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 162 -------------------------------------------------- site=BRID GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 1.77 0.80 0.72503 0.27 37.3 0.07 10.3 0.28 38.3 0.01 1.43 0.09 12.7 1990 2.91 1.13 1.17179 0.38 32.5 0.07 6.35 0.52 44.3 0.02 2.09 0.17 14.8 1991 3.26 2.15 0.89404 0.27 29.7 0.07 8.33 0.35 39.1 0.02 2.04 0.19 20.8 1992 3.05 1.91 0.92135 0.36 38.9 0.07 8.08 0.29 31.2 0.03 2.92 0.17 18.9 1993 2.16 1.30 0.76040 0.32 41.5 0.07 9.79 0.25 32.6 0.02 2.36 0.10 13.7 1994 2.17 1.02 0.85534 0.36 41.9 0.07 8.70 0.25 29.6 0.03 3.98 0.14 15.8 1995 1.85 1.01 0.92668 0.29 31.5 0.07 8.03 0.36 39.2 0.04 4.47 0.16 16.8 1996 1.84 0.94 0.79737 0.29 36.0 0.07 9.34 0.29 36.9 0.05 5.90 0.10 11.9 1997 2.37 1.29 0.86920 0.30 34.2 0.07 8.56 0.35 40.1 0.03 3.65 0.12 13.5 1998 2.99 1.93 0.95994 0.38 39.3 0.07 7.76 0.38 39.1 0.04 4.02 0.09 9.87 1999 2.01 1.26 0.95978 0.30 31.2 0.07 7.76 0.38 39.9 0.05 5.14 0.15 16.0 -------------------------------------------------- site=BRID GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 5.60 2.87 2.10183 0.72 34.3 0.13 6.07 0.74 35.1 0.07 3.36 0.45 21.2 1990 5.27 3.01 2.06860 0.76 36.6 0.13 6.17 0.77 37.4 0.07 3.30 0.34 16.5 1991 7.03 4.15 2.23382 0.74 33.1 0.13 5.71 0.89 39.6 0.06 2.83 0.42 18.8 1992 5.63 3.48 1.93354 0.77 39.7 0.13 6.60 0.69 35.6 0.05 2.74 0.30 15.4 1993 5.34 3.27 1.79060 0.69 38.7 0.13 7.13 0.61 34.0 0.05 2.61 0.31 17.6 1994 5.46 2.87 2.09133 0.67 32.1 0.13 6.10 0.77 37.0 0.07 3.45 0.45 21.4 1995 4.35 2.13 1.88789 0.64 34.0 0.13 6.76 0.72 38.3 0.11 5.96 0.28 15.0 1996 4.55 2.35 1.95719 0.57 29.3 0.13 6.52 0.76 38.6 0.11 5.46 0.39 20.1 1997 4.84 2.77 1.65414 0.58 35.0 0.13 7.72 0.61 36.9 0.07 4.28 0.27 16.2 1998 5.17 2.90 2.28451 0.72 31.4 0.13 5.59 1.03 45.2 0.09 4.11 0.31 13.7 1999 6.10 3.48 2.17963 0.61 27.9 0.13 5.86 0.87 39.9 0.12 5.42 0.46 21.0 -------------------------------------------------- site=BRID GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 10.42 5.46 4.03124 1.43 35.4 0.20 4.97 1.32 32.8 0.22 5.40 0.86 21.4 1990 14.18 8.92 3.96663 1.29 32.6 0.20 5.05 1.51 38.1 0.13 3.18 0.84 21.1 1991 12.79 7.70 3.86854 1.18 30.5 0.20 5.18 1.24 32.1 0.10 2.64 1.14 29.6 1992 11.27 5.96 4.46859 1.36 30.3 0.20 4.48 1.54 34.5 0.16 3.62 1.21 27.1 1993 7.01 3.41 3.22139 1.32 40.8 0.20 6.22 1.00 31.2 0.11 3.32 0.59 18.5 1994 9.20 3.79 4.68218 1.12 23.9 0.20 4.28 2.08 44.5 0.18 3.80 1.10 23.5 1995 7.49 3.88 3.17068 1.01 32.0 0.20 6.32 1.24 39.0 0.20 6.33 0.52 16.3 1996 11.50 5.40 5.08571 1.23 24.2 0.20 3.94 2.45 48.2 0.28 5.41 0.93 18.3 1997 9.39 5.77 2.94407 1.12 38.0 0.20 6.80 0.93 31.5 0.13 4.32 0.57 19.4 1998 8.09 3.47 4.65293 1.20 25.9 0.20 4.31 2.15 46.3 0.18 3.90 0.91 19.7 1999 10.51 5.99 4.35028 0.97 22.2 0.20 4.60 1.99 45.7 0.17 3.92 1.03 23.6 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 163 -------------------------------------------------- site=BRIG GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 13.74 7.32 5.40395 2.77 51.3 0.43 7.97 1.56 28.8 0.37 6.85 0.27 5.07 1994 15.83 10.06 4.68543 2.07 44.2 0.43 9.19 1.41 30.1 0.38 8.15 0.39 8.34 1995 12.90 7.24 3.94759 2.18 55.3 0.43 10.9 0.89 22.5 0.23 5.78 0.22 5.52 1997 17.70 11.71 4.11434 2.10 51.1 0.43 10.5 1.04 25.3 0.27 6.52 0.27 6.55 1998 13.85 8.57 3.87548 1.92 49.6 0.43 11.1 1.04 26.8 0.26 6.58 0.23 5.87 1999 12.25 7.40 3.65579 1.51 41.2 0.43 11.8 1.20 32.9 0.29 7.89 0.23 6.21 -------------------------------------------------- site=BRIG GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 17.13 6.40 10.2000 5.69 55.8 0.96 9.42 2.63 25.8 0.58 5.68 0.34 3.37 1994 22.87 11.05 10.5421 5.11 48.5 0.96 9.11 2.99 28.3 0.70 6.63 0.78 7.42 1995 19.73 10.94 8.0735 4.23 52.4 0.96 11.9 1.92 23.8 0.61 7.50 0.35 4.39 1997 22.53 12.20 8.9523 4.98 55.7 0.96 10.7 2.18 24.4 0.46 5.18 0.36 4.02 1998 20.66 12.40 8.1493 4.16 51.1 0.96 11.8 2.11 25.9 0.51 6.24 0.41 5.01 1999 19.31 10.52 7.8798 3.95 50.1 0.96 12.2 2.16 27.4 0.45 5.68 0.36 4.56 -------------------------------------------------- site=BRIG GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 29.34 9.10 20.2036 14.05 69.5 0.74 3.68 4.11 20.3 0.74 3.64 0.57 2.81 1994 35.42 13.41 21.0290 14.25 67.7 0.74 3.54 4.19 19.9 0.77 3.65 1.08 5.13 1995 37.44 17.91 17.2581 11.84 68.6 0.74 4.31 3.46 20.0 0.63 3.64 0.58 3.38 1997 42.17 19.86 18.9622 12.85 67.8 0.74 3.92 4.03 21.3 0.61 3.24 0.72 3.78 1998 35.73 11.82 21.5596 14.34 66.5 0.74 3.45 4.85 22.5 0.89 4.11 0.74 3.44 1999 32.77 11.94 18.1867 11.16 61.3 0.74 4.09 4.80 26.4 0.72 3.95 0.77 4.24 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 164 -------------------------------------------------- site=CANY GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 4.99 2.36 1.82514 0.72 39.7 0.10 5.33 0.43 23.5 0.05 2.62 0.53 28.8 1991 6.38 3.68 1.79461 0.70 38.9 0.10 5.42 0.48 26.6 0.03 1.65 0.49 27.4 1992 5.51 3.17 1.81648 0.74 41.0 0.10 5.36 0.46 25.3 0.05 2.85 0.46 25.5 1993 4.83 2.52 1.76922 0.73 41.1 0.10 5.50 0.47 26.3 0.05 3.05 0.43 24.1 1994 5.16 3.04 1.72114 0.75 43.6 0.10 5.65 0.47 27.4 0.07 4.06 0.33 19.3 1995 4.83 3.01 1.48588 0.51 34.6 0.10 6.55 0.40 26.8 0.09 6.22 0.38 25.8 1996 3.66 2.41 1.04394 0.41 39.4 0.10 9.32 0.27 26.0 0.07 6.95 0.19 18.4 1997 6.12 3.89 1.48301 0.55 36.9 0.10 6.56 0.43 29.2 0.08 5.14 0.33 22.2 1998 4.71 2.77 1.57470 0.54 34.1 0.10 6.18 0.47 29.7 0.09 5.63 0.38 24.3 1999 4.92 2.87 1.58860 0.58 36.2 0.10 6.12 0.42 26.6 0.08 4.76 0.42 26.3 -------------------------------------------------- site=CANY GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 6.96 3.27 2.83360 1.23 43.5 0.18 6.46 0.78 27.6 0.12 4.36 0.51 18.1 1991 12.16 8.09 3.44436 1.21 35.1 0.18 5.31 0.79 23.0 0.10 2.93 1.16 33.6 1992 7.28 4.18 2.72373 1.16 42.7 0.18 6.72 0.71 26.1 0.10 3.73 0.57 20.8 1993 9.70 6.38 2.83930 1.15 40.5 0.18 6.44 0.71 24.9 0.09 3.19 0.71 25.0 1994 8.75 5.29 2.94607 1.24 42.0 0.18 6.21 0.75 25.4 0.12 3.95 0.66 22.4 1995 6.73 4.09 2.32774 0.90 38.5 0.18 7.86 0.57 24.5 0.13 5.64 0.55 23.5 1996 8.05 4.80 2.83055 0.84 29.7 0.18 6.46 0.82 28.8 0.16 5.64 0.83 29.3 1997 10.18 6.80 2.67908 1.10 41.2 0.18 6.83 0.62 23.0 0.12 4.49 0.66 24.5 1998 6.77 4.04 2.61875 0.99 37.8 0.18 6.99 0.85 32.6 0.15 5.70 0.44 16.8 1999 6.28 3.52 2.32674 0.91 39.2 0.18 7.86 0.68 29.4 0.12 4.99 0.43 18.6 -------------------------------------------------- site=CANY GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 18.53 12.79 4.86784 1.66 34.2 0.40 8.14 1.24 25.5 0.18 3.69 1.39 28.5 1991 14.98 10.03 4.21931 1.90 45.1 0.40 9.39 1.41 33.5 0.27 6.33 0.24 5.68 1992 11.45 6.30 4.31134 1.94 44.9 0.40 9.19 1.34 31.0 0.23 5.40 0.41 9.50 1993 12.48 7.60 4.31016 1.71 39.6 0.40 9.19 1.17 27.3 0.16 3.71 0.87 20.2 1994 14.13 9.22 4.56037 1.42 31.1 0.40 8.69 1.27 27.9 0.16 3.42 1.32 29.0 1995 10.63 6.51 3.82450 1.42 37.3 0.40 10.4 1.15 30.1 0.20 5.25 0.65 17.1 1996 15.41 9.00 5.54405 1.52 27.3 0.40 7.14 1.94 35.1 0.31 5.53 1.38 24.9 1997 13.06 8.81 3.75202 1.53 40.7 0.40 10.6 0.97 25.8 0.20 5.44 0.66 17.5 1998 13.39 8.77 4.29234 1.56 36.3 0.40 9.23 1.35 31.4 0.21 4.89 0.78 18.2 1999 15.60 10.41 4.48752 1.04 23.2 0.40 8.83 1.34 29.8 0.19 4.29 1.52 33.9 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 165 -------------------------------------------------- site=CHAS GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 14.28 8.43 4.80408 2.02 42.1 0.42 8.66 1.53 31.9 0.33 6.79 0.51 10.6 1995 13.00 7.80 4.36215 1.77 40.6 0.42 9.54 1.42 32.6 0.32 7.28 0.44 9.99 1996 14.60 8.42 5.65564 2.25 39.8 0.42 7.36 1.74 30.8 0.41 7.30 0.83 14.7 1997 12.57 7.22 4.80002 1.99 41.4 0.42 8.67 1.69 35.2 0.40 8.34 0.31 6.43 1998 15.55 8.96 5.73150 2.47 43.1 0.42 7.26 1.83 31.9 0.36 6.30 0.66 11.5 1999 12.81 6.38 5.32744 2.05 38.5 0.42 7.81 2.01 37.6 0.41 7.60 0.45 8.47 -------------------------------------------------- site=CHAS GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 16.70 7.58 8.41952 3.93 46.6 0.47 5.62 2.74 32.6 0.76 8.97 0.52 6.21 1995 19.95 10.13 8.83588 3.75 42.5 0.47 5.36 2.41 27.3 0.74 8.42 1.46 16.5 1996 17.70 9.03 7.97993 3.99 50.1 0.47 5.93 2.22 27.9 0.58 7.22 0.71 8.91 1997 20.45 10.21 9.42087 4.74 50.3 0.47 5.02 2.39 25.4 0.53 5.61 1.29 13.7 1998 22.34 11.52 9.98920 4.17 41.7 0.47 4.74 2.77 27.7 0.54 5.36 2.04 20.5 1999 17.64 6.58 9.37019 4.71 50.2 0.47 5.05 3.00 32.0 0.75 8.01 0.44 4.71 -------------------------------------------------- site=CHAS GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 25.78 7.27 16.5895 9.26 55.8 0.40 2.41 4.36 26.3 0.91 5.48 1.66 10.0 1995 24.25 8.39 14.3390 8.69 60.6 0.40 2.79 3.28 22.9 0.78 5.42 1.19 8.28 1996 24.50 11.33 12.0321 7.61 63.3 0.40 3.33 2.74 22.8 0.66 5.47 0.62 5.14 1997 23.34 7.01 14.5973 9.04 61.9 0.40 2.74 3.78 25.9 0.72 4.94 0.66 4.51 1998 26.57 10.09 15.5114 8.51 54.9 0.40 2.58 3.69 23.8 0.73 4.69 2.19 14.1 1999 26.23 8.98 14.6481 9.21 62.9 0.40 2.73 3.61 24.7 0.63 4.33 0.79 5.38 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 166 -------------------------------------------------- site=CHIR GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 6.70 4.15 1.93882 0.68 35.1 0.13 6.51 0.54 28.1 0.06 3.12 0.53 27.2 1992 5.55 3.26 1.92865 0.81 42.0 0.13 6.55 0.49 25.4 0.08 4.10 0.42 21.9 1993 4.01 2.16 1.68179 0.74 44.3 0.13 7.51 0.45 27.0 0.09 5.40 0.27 15.9 1994 6.33 3.81 1.80883 0.70 38.5 0.13 6.98 0.42 23.4 0.09 5.23 0.47 25.9 1995 5.73 3.28 2.07978 0.73 34.9 0.13 6.07 0.54 26.2 0.11 5.41 0.57 27.5 1996 5.60 3.10 1.85631 0.62 33.6 0.13 6.80 0.48 25.6 0.07 3.94 0.56 30.1 1997 5.65 3.34 1.95953 0.88 44.8 0.13 6.45 0.48 24.6 0.07 3.73 0.40 20.4 1998 5.07 2.82 1.84640 0.64 34.7 0.13 6.84 0.60 32.5 0.09 5.14 0.38 20.8 1999 5.63 3.21 1.99581 0.61 30.6 0.13 6.33 0.53 26.5 0.09 4.75 0.63 31.8 -------------------------------------------------- site=CHIR GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 10.45 6.44 3.33931 1.33 39.9 0.17 5.22 0.85 25.3 0.12 3.47 0.87 26.1 1992 9.00 5.39 2.99653 1.40 46.9 0.17 5.81 0.82 27.5 0.13 4.34 0.47 15.5 1993 8.73 4.78 3.48228 1.45 41.5 0.17 5.00 0.85 24.5 0.13 3.61 0.88 25.4 1994 9.29 4.87 3.55646 1.68 47.1 0.17 4.90 0.80 22.6 0.13 3.59 0.77 21.8 1995 10.84 7.28 3.11789 1.20 38.5 0.17 5.59 0.72 23.1 0.13 4.17 0.89 28.7 1996 10.21 6.09 3.61998 1.55 42.8 0.17 4.81 0.76 21.0 0.12 3.31 1.02 28.0 1997 9.16 5.04 3.42451 1.55 45.2 0.17 5.09 0.68 19.8 0.12 3.38 0.91 26.5 1998 9.70 5.40 3.79668 1.41 37.0 0.17 4.59 1.13 29.8 0.13 3.42 0.96 25.2 1999 9.09 5.23 3.30537 1.29 38.9 0.17 5.27 0.84 25.5 0.15 4.41 0.86 26.0 -------------------------------------------------- site=CHIR GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 16.41 10.55 4.92541 2.30 46.6 0.21 4.28 1.30 26.4 0.15 2.96 0.97 19.7 1992 11.11 5.41 5.22621 2.29 43.9 0.21 4.03 1.74 33.2 0.29 5.57 0.69 13.3 1993 13.42 6.57 5.90635 2.73 46.3 0.21 3.57 1.83 31.0 0.22 3.79 0.91 15.3 1994 15.33 8.01 6.09759 2.44 40.0 0.21 3.46 1.83 30.1 0.23 3.69 1.39 22.8 1995 13.77 7.21 5.91430 3.00 50.8 0.21 3.56 1.36 23.0 0.23 3.82 1.12 18.9 1996 16.09 9.82 5.64248 2.50 44.3 0.21 3.73 1.37 24.3 0.18 3.19 1.38 24.5 1997 12.15 6.07 4.81163 2.87 59.7 0.21 4.38 0.85 17.6 0.12 2.41 0.76 15.9 1998 16.31 8.35 6.96169 3.14 45.1 0.21 3.03 2.31 33.2 0.22 3.23 1.08 15.5 1999 14.53 8.58 5.38933 2.12 39.3 0.21 3.91 1.38 25.6 0.19 3.49 1.49 27.7 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 167 -------------------------------------------------- site=CRLA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 2.87 1.87 0.88174 0.26 29.8 0.04 4.70 0.36 40.9 0.09 10.1 0.13 14.4 1993 2.68 1.92 0.92844 0.26 28.3 0.04 4.46 0.35 37.8 0.09 9.69 0.18 19.8 1995 1.27 0.87 0.59968 0.15 24.8 0.04 6.91 0.24 39.2 0.09 14.4 0.09 14.6 1996 2.29 1.87 0.71334 0.16 21.8 0.04 5.81 0.32 45.0 0.08 10.6 0.12 16.7 1997 2.80 1.70 0.69392 0.20 28.5 0.04 5.97 0.32 45.7 0.06 7.96 0.08 11.8 1998 2.36 1.86 0.69157 0.13 19.4 0.04 5.99 0.34 48.8 0.08 11.0 0.10 14.8 1999 2.10 1.45 0.76066 0.19 24.7 0.04 5.45 0.30 40.0 0.06 7.73 0.17 22.1 -------------------------------------------------- site=CRLA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 5.94 3.41 1.95965 0.50 25.4 0.09 4.76 0.84 42.9 0.19 9.53 0.34 17.4 1993 5.59 3.40 1.89424 0.50 26.4 0.09 4.92 0.69 36.6 0.13 7.03 0.47 25.0 1995 3.94 2.32 1.69521 0.39 23.2 0.09 5.50 0.67 39.5 0.21 12.5 0.33 19.2 1996 4.94 3.04 1.70029 0.39 23.2 0.09 5.48 0.68 40.2 0.20 11.6 0.33 19.5 1997 5.31 3.15 1.63691 0.40 24.2 0.09 5.70 0.78 47.6 0.15 9.19 0.22 13.2 1998 4.51 3.58 1.23017 0.24 19.1 0.09 7.58 0.58 47.1 0.12 9.96 0.20 16.3 1999 3.34 1.79 1.32026 0.26 19.9 0.09 7.06 0.61 46.2 0.14 10.4 0.22 16.4 -------------------------------------------------- site=CRLA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 11.94 6.53 4.12954 1.14 27.7 0.20 4.79 1.65 39.9 0.28 6.79 0.86 20.8 1993 10.69 5.85 4.32433 1.14 26.5 0.20 4.57 1.79 41.3 0.38 8.68 0.82 19.0 1995 8.10 3.42 4.27575 0.84 19.7 0.20 4.62 1.81 42.4 0.54 12.5 0.89 20.7 1996 16.74 9.08 6.43089 0.88 13.8 0.20 3.07 3.74 58.2 0.60 9.30 1.01 15.7 1997 9.68 5.39 3.58938 0.76 21.2 0.20 5.51 1.94 54.1 0.27 7.59 0.42 11.7 1998 11.09 5.58 5.18697 0.95 18.2 0.20 3.81 2.49 47.9 0.29 5.60 1.27 24.4 1999 11.16 5.12 5.10516 0.58 11.3 0.20 3.87 3.48 68.1 0.36 6.96 0.50 9.80 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 168 -------------------------------------------------- site=DENA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 2.60 1.81 0.69900 0.21 29.5 0.03 3.86 0.30 42.4 0.02 2.73 0.15 21.5 1991 2.56 1.30 0.80511 0.24 29.2 0.03 3.35 0.36 45.1 0.02 2.71 0.16 19.6 1992 2.79 1.70 0.62572 0.25 40.6 0.03 4.31 0.20 32.8 0.03 4.36 0.11 18.0 1993 3.20 2.04 0.80128 0.24 29.5 0.03 3.37 0.28 34.4 0.03 3.32 0.24 29.4 1994 2.53 1.39 0.68540 0.28 40.9 0.03 3.94 0.19 27.3 0.04 5.16 0.16 22.6 1995 2.33 1.86 0.60749 0.23 38.2 0.03 4.44 0.13 21.9 0.03 4.42 0.19 31.0 1996 2.82 2.10 0.65599 0.21 32.0 0.03 4.11 0.26 39.5 0.04 6.66 0.12 17.7 1997 3.85 2.41 0.72026 0.26 36.5 0.03 3.75 0.26 36.0 0.06 8.15 0.11 15.6 1998 2.69 1.69 0.58864 0.16 27.2 0.03 4.58 0.25 41.8 0.04 6.09 0.12 20.4 1999 2.16 1.76 0.54753 0.21 37.7 0.03 4.93 0.16 28.4 0.04 6.59 0.12 22.3 -------------------------------------------------- site=DENA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 5.10 3.34 1.51313 0.57 37.4 0.05 3.39 0.61 40.1 0.08 5.06 0.21 14.0 1991 3.42 2.10 1.15086 0.41 36.0 0.05 4.45 0.46 40.3 0.04 3.71 0.18 15.5 1992 3.45 1.95 1.02175 0.40 38.8 0.05 5.02 0.39 37.8 0.07 6.75 0.12 11.6 1993 3.42 1.98 1.09350 0.40 36.5 0.05 4.69 0.43 39.2 0.06 5.09 0.16 14.5 1994 3.57 2.10 1.07080 0.42 39.6 0.05 4.79 0.41 37.9 0.06 5.36 0.13 12.3 1995 3.06 2.17 0.85192 0.32 38.1 0.05 6.02 0.27 31.5 0.10 12.3 0.10 12.1 1996 4.28 2.84 1.32710 0.53 40.2 0.05 3.86 0.46 34.6 0.08 6.27 0.20 15.1 1997 5.04 3.21 1.27259 0.43 33.9 0.05 4.03 0.52 41.2 0.10 8.24 0.16 12.6 1998 2.60 2.03 0.99638 0.32 32.0 0.05 5.14 0.39 38.6 0.06 5.70 0.18 18.5 1999 3.28 1.98 1.23190 0.51 41.7 0.05 4.16 0.38 31.2 0.09 7.08 0.20 15.9 -------------------------------------------------- site=DENA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 11.81 8.85 2.45323 0.93 37.9 0.10 4.17 0.86 35.1 0.12 4.97 0.44 17.9 1991 11.56 6.01 4.06691 0.87 21.4 0.10 2.51 2.73 67.2 0.22 5.30 0.15 3.62 1992 6.30 3.35 2.24255 1.23 54.6 0.10 4.56 0.60 26.7 0.13 5.66 0.19 8.46 1993 8.52 3.75 3.56691 0.97 27.2 0.10 2.87 2.06 57.8 0.19 5.41 0.24 6.72 1994 7.39 3.33 3.00822 1.09 36.3 0.10 3.40 1.45 48.2 0.15 5.10 0.21 7.02 1995 6.36 3.57 2.33485 1.25 53.6 0.10 4.38 0.56 23.9 0.14 5.81 0.29 12.3 1996 7.14 4.36 2.57350 0.98 37.9 0.10 3.97 1.02 39.7 0.17 6.63 0.30 11.8 1997 11.06 5.70 3.94851 0.89 22.4 0.10 2.59 2.48 62.8 0.29 7.30 0.19 4.86 1998 6.11 4.01 1.94237 0.55 28.4 0.10 5.26 0.93 48.0 0.12 6.03 0.24 12.4 1999 7.53 4.74 2.43861 0.71 29.2 0.10 4.19 1.15 47.3 0.14 5.73 0.33 13.6 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 169 -------------------------------------------------- site=DOSO GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 8.10 4.58 3.33258 1.43 42.9 0.32 9.66 1.00 29.9 0.21 6.35 0.37 11.2 1995 6.09 1.96 3.88975 2.00 51.5 0.32 8.28 1.15 29.4 0.22 5.64 0.20 5.12 1996 8.87 3.84 4.60660 2.36 51.1 0.32 6.99 1.40 30.4 0.27 5.96 0.26 5.55 1997 10.55 4.23 4.43403 2.08 46.9 0.32 7.26 1.50 33.9 0.30 6.80 0.23 5.16 1998 7.97 2.90 3.72703 1.58 42.5 0.32 8.64 1.31 35.2 0.27 7.22 0.24 6.48 1999 9.29 4.12 4.28295 1.96 45.7 0.32 7.52 1.45 33.7 0.26 6.07 0.30 6.94 -------------------------------------------------- site=DOSO GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 15.33 5.77 9.10893 5.25 57.6 0.43 4.74 2.59 28.4 0.42 4.57 0.42 4.64 1995 14.31 4.81 8.41086 4.63 55.1 0.43 5.14 2.31 27.4 0.43 5.14 0.61 7.22 1996 11.94 4.13 7.63660 4.48 58.7 0.43 5.66 2.05 26.9 0.40 5.25 0.27 3.55 1997 13.81 3.98 8.11946 4.72 58.2 0.43 5.32 2.23 27.5 0.43 5.24 0.31 3.79 1998 13.05 3.83 8.54905 4.06 47.5 0.43 5.06 3.17 37.1 0.48 5.60 0.40 4.71 1999 13.38 3.71 8.07138 4.26 52.7 0.43 5.35 2.64 32.8 0.43 5.28 0.31 3.86 -------------------------------------------------- site=DOSO GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1994 37.78 7.96 25.0461 19.85 79.3 0.26 1.03 3.77 15.0 0.41 1.65 0.76 3.02 1995 31.99 5.48 23.2821 17.76 76.3 0.26 1.11 3.92 16.8 0.56 2.42 0.78 3.36 1996 27.63 4.74 19.0150 14.61 76.8 0.26 1.36 3.10 16.3 0.45 2.36 0.60 3.15 1997 28.08 4.57 19.8321 15.40 77.7 0.26 1.30 3.05 15.4 0.41 2.08 0.70 3.55 1998 31.18 3.63 22.5641 17.06 75.6 0.26 1.15 4.03 17.9 0.64 2.84 0.58 2.55 1999 21.31 2.74 18.1477 13.25 73.0 0.26 1.42 3.50 19.3 0.48 2.65 0.66 3.63 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 170 -------------------------------------------------- site=GICL GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 3.74 2.15 1.29938 0.44 34.1 0.07 5.10 0.33 25.6 0.07 5.70 0.38 29.5 1997 4.00 2.47 1.22503 0.55 45.1 0.07 5.41 0.36 29.4 0.08 6.85 0.16 13.3 1998 4.98 3.24 1.49457 0.58 38.5 0.07 4.43 0.46 31.1 0.09 5.81 0.30 20.2 1999 5.37 3.50 1.44657 0.45 31.3 0.07 4.58 0.44 30.6 0.09 6.44 0.39 27.1 -------------------------------------------------- site=GICL GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 10.01 6.48 3.03815 1.05 34.6 0.13 4.25 0.78 25.7 0.13 4.19 0.95 31.2 1997 8.76 5.11 3.05674 1.36 44.4 0.13 4.22 1.01 33.1 0.16 5.09 0.40 13.2 1998 8.95 5.63 3.22789 1.20 37.2 0.13 4.00 0.99 30.6 0.17 5.37 0.74 22.9 1999 9.20 5.19 3.24524 1.13 34.7 0.13 3.98 0.94 28.9 0.16 4.92 0.89 27.5 -------------------------------------------------- site=GICL GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 16.72 8.22 7.69277 2.33 30.2 0.15 1.95 4.03 52.4 0.51 6.58 0.68 8.86 1997 15.21 6.79 7.52488 2.07 27.5 0.15 2.00 3.97 52.8 0.51 6.74 0.83 11.0 1998 14.45 5.39 9.05000 2.61 28.8 0.15 1.66 5.00 55.3 0.64 7.05 0.65 7.19 1999 11.93 6.56 4.74930 1.92 40.3 0.15 3.17 1.61 33.8 0.20 4.11 0.88 18.6 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 171 -------------------------------------------------- site=GLAC GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 4.59 2.11 2.13282 0.55 25.7 0.09 4.39 1.13 53.2 0.19 8.93 0.17 7.81 1990 4.25 1.75 1.85809 0.51 27.3 0.09 5.04 0.95 51.4 0.14 7.38 0.16 8.84 1991 8.15 5.33 2.43170 0.58 24.0 0.09 3.85 1.22 50.2 0.14 5.84 0.39 16.0 1992 6.57 3.97 2.16738 0.50 23.2 0.09 4.32 1.13 52.3 0.17 7.82 0.27 12.3 1993 6.00 3.09 2.33429 0.55 23.4 0.09 4.01 1.29 55.5 0.17 7.18 0.23 9.96 1994 4.99 2.93 1.93702 0.52 27.1 0.09 4.84 0.95 48.9 0.14 7.19 0.23 12.0 1995 4.12 2.25 1.75998 0.40 22.5 0.09 5.32 0.88 50.2 0.20 11.5 0.18 10.4 1996 3.97 1.78 1.91815 0.43 22.6 0.09 4.88 0.99 51.6 0.19 9.98 0.21 10.9 1997 4.86 1.81 1.89545 0.43 22.7 0.09 4.94 1.02 54.1 0.16 8.47 0.19 9.82 1998 3.85 1.72 2.04909 0.37 17.9 0.09 4.57 1.21 59.0 0.21 10.1 0.17 8.42 1999 3.61 1.73 1.64270 0.40 24.3 0.09 5.70 0.83 50.7 0.16 9.91 0.16 9.47 -------------------------------------------------- site=GLAC GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 11.97 6.19 4.83352 1.08 22.3 0.17 3.51 2.63 54.4 0.36 7.49 0.59 12.3 1990 9.86 4.26 4.66449 1.15 24.7 0.17 3.64 2.42 51.9 0.37 8.01 0.55 11.7 1991 15.49 9.75 4.62838 0.91 19.8 0.17 3.67 2.53 54.7 0.34 7.36 0.67 14.5 1992 11.75 6.13 4.75958 1.16 24.4 0.17 3.57 2.48 52.1 0.38 7.96 0.57 11.9 1993 9.08 4.08 4.29974 1.20 27.9 0.17 3.95 2.28 53.1 0.29 6.80 0.36 8.28 1994 11.20 5.45 4.85867 0.92 18.9 0.17 3.49 2.65 54.5 0.41 8.40 0.71 14.7 1995 9.73 5.41 3.75073 1.00 26.7 0.17 4.52 1.70 45.3 0.35 9.28 0.53 14.2 1996 9.98 5.50 3.92788 1.06 26.9 0.17 4.32 1.92 48.8 0.33 8.48 0.45 11.5 1997 10.56 6.26 3.72959 0.80 21.5 0.17 4.55 2.03 54.3 0.30 8.17 0.43 11.5 1998 9.90 5.25 4.31212 1.01 23.5 0.17 3.94 2.32 53.7 0.38 8.74 0.44 10.1 1999 10.19 5.99 3.69958 0.78 21.1 0.17 4.59 1.94 52.4 0.31 8.48 0.50 13.4 -------------------------------------------------- site=GLAC GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 17.96 6.91 9.3589 1.59 17.0 0.40 4.32 5.71 61.1 0.92 9.88 0.72 7.70 1990 23.63 11.83 9.7525 1.33 13.7 0.40 4.14 6.14 63.0 0.98 10.1 0.89 9.15 1991 26.09 13.23 9.9630 1.50 15.0 0.40 4.06 6.13 61.6 0.72 7.26 1.21 12.1 1992 25.12 14.06 9.1810 1.72 18.8 0.40 4.40 4.66 50.8 0.67 7.26 1.72 18.8 1993 15.66 4.44 9.1580 1.70 18.6 0.40 4.41 5.79 63.2 0.74 8.04 0.53 5.74 1994 23.39 10.42 10.4323 1.29 12.3 0.40 3.87 6.84 65.6 0.86 8.26 1.04 9.96 1995 21.34 11.34 7.9979 1.28 16.0 0.40 5.05 4.69 58.6 0.69 8.66 0.93 11.7 1996 13.80 4.92 7.5677 1.77 23.4 0.40 5.34 4.30 56.8 0.61 8.00 0.49 6.44 1997 14.17 6.20 6.9233 1.75 25.3 0.40 5.84 3.70 53.5 0.52 7.50 0.55 7.88 1998 32.70 19.45 11.7904 1.27 10.7 0.40 3.43 7.27 61.7 0.81 6.88 2.03 17.2 1999 36.12 24.43 9.4882 1.27 13.4 0.40 4.26 4.97 52.4 0.59 6.24 2.25 23.7 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 172 -------------------------------------------------- site=GRBA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 4.41 2.52 1.51398 0.44 29.3 0.06 3.86 0.53 34.8 0.09 6.18 0.39 25.8 1994 3.70 2.20 1.28389 0.31 23.8 0.06 4.55 0.51 39.8 0.11 8.87 0.30 23.0 1995 2.60 1.77 0.85577 0.21 24.1 0.06 6.83 0.35 40.7 0.06 7.40 0.18 20.9 1996 2.71 1.71 0.85584 0.20 23.0 0.06 6.83 0.36 41.5 0.07 8.23 0.17 20.3 1997 2.87 1.47 1.05811 0.30 28.0 0.06 5.52 0.43 40.8 0.06 5.54 0.21 20.1 1998 2.72 1.65 1.17995 0.29 24.9 0.06 4.95 0.54 45.4 0.09 7.69 0.20 17.1 1999 3.59 1.90 1.51452 0.30 19.8 0.06 3.86 0.54 35.4 0.09 5.87 0.53 35.1 -------------------------------------------------- site=GRBA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 7.78 4.37 2.82346 0.77 27.2 0.13 4.50 1.08 38.3 0.12 4.26 0.73 25.7 1994 6.94 3.97 2.64395 0.64 24.4 0.13 4.81 0.98 36.9 0.12 4.65 0.77 29.3 1995 5.37 3.20 2.01498 0.47 23.5 0.13 6.31 0.72 35.6 0.16 8.11 0.53 26.5 1996 6.16 3.68 2.09160 0.53 25.1 0.13 6.08 0.80 38.1 0.15 7.35 0.49 23.3 1997 5.67 3.16 1.80879 0.50 27.6 0.13 7.02 0.72 39.6 0.12 6.74 0.34 19.1 1998 6.50 4.34 2.23432 0.57 25.7 0.13 5.69 0.98 43.9 0.17 7.83 0.38 16.9 1999 6.14 2.72 2.85546 0.71 24.9 0.13 4.45 1.03 36.1 0.15 5.19 0.84 29.4 -------------------------------------------------- site=GRBA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1993 10.41 5.44 4.36271 1.22 28.0 0.29 6.65 1.75 40.1 0.26 5.91 0.84 19.4 1994 12.90 7.01 4.47451 1.25 27.8 0.29 6.49 1.38 30.8 0.14 3.04 1.43 31.9 1995 9.18 4.99 3.72956 1.22 32.8 0.29 7.78 1.04 27.9 0.20 5.46 0.97 26.0 1996 12.67 5.99 5.51217 1.11 20.2 0.29 5.26 2.55 46.2 0.32 5.85 1.24 22.4 1997 9.08 4.88 3.70560 1.23 33.3 0.29 7.83 1.28 34.6 0.20 5.48 0.70 18.9 1998 8.74 4.71 4.25955 1.25 29.4 0.29 6.81 1.62 38.0 0.23 5.42 0.87 20.4 1999 9.72 4.60 4.84557 0.93 19.2 0.29 5.99 2.18 45.0 0.31 6.30 1.14 23.5 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 173 -------------------------------------------------- site=GRCA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 3.90 1.77 1.34929 0.49 36.0 0.07 5.20 0.41 30.5 0.06 4.37 0.32 23.9 1991 4.49 2.43 1.44434 0.50 34.4 0.07 4.86 0.49 34.2 0.06 3.96 0.33 22.6 1993 4.29 2.24 1.29769 0.47 36.6 0.07 5.41 0.41 31.6 0.04 2.93 0.31 23.5 1994 3.32 1.57 1.28160 0.50 38.7 0.07 5.47 0.38 30.0 0.06 4.41 0.27 21.4 1995 3.64 2.29 1.23786 0.41 33.4 0.07 5.67 0.35 28.3 0.09 7.13 0.32 25.6 1996 4.44 2.82 1.25388 0.41 32.4 0.07 5.60 0.33 26.5 0.07 5.73 0.37 29.8 1997 4.02 2.39 1.14994 0.45 39.3 0.07 6.10 0.31 27.0 0.10 8.44 0.22 19.2 -------------------------------------------------- site=GRCA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 8.74 5.41 3.02918 1.06 35.0 0.19 6.22 0.84 27.6 0.13 4.34 0.81 26.8 1991 8.28 4.72 2.89766 1.03 35.7 0.19 6.50 0.82 28.4 0.13 4.44 0.72 25.0 1993 7.66 4.40 2.35506 0.92 39.0 0.19 8.00 0.62 26.4 0.09 3.79 0.54 22.9 1994 6.28 3.12 2.57738 1.09 42.1 0.19 7.31 0.76 29.5 0.13 5.16 0.41 15.9 1995 7.01 4.60 2.26540 0.82 36.3 0.19 8.32 0.66 29.0 0.16 7.00 0.44 19.4 1996 8.77 5.60 2.60674 0.85 32.5 0.19 7.23 0.68 26.0 0.15 5.68 0.74 28.6 1997 7.80 4.82 2.44989 0.84 34.3 0.19 7.69 0.59 24.1 0.14 5.56 0.69 28.3 -------------------------------------------------- site=GRCA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 20.43 14.68 5.08010 1.80 35.5 0.28 5.53 1.46 28.7 0.25 4.98 1.28 25.3 1991 12.51 7.53 4.05048 1.72 42.4 0.28 6.94 1.03 25.4 0.18 4.34 0.85 20.9 1993 11.15 5.89 4.46555 1.45 32.5 0.28 6.30 1.83 41.0 0.22 4.85 0.69 15.4 1994 11.82 6.36 4.69173 1.63 34.7 0.28 5.99 1.44 30.8 0.25 5.28 1.09 23.2 1995 13.15 8.77 3.96308 1.73 43.6 0.28 7.09 1.09 27.5 0.21 5.34 0.65 16.5 1996 15.02 9.94 4.44697 1.64 36.8 0.28 6.32 1.29 28.9 0.23 5.27 1.01 22.6 1997 12.95 8.85 3.62900 1.66 45.8 0.28 7.75 0.76 21.1 0.19 5.23 0.73 20.2 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 174 -------------------------------------------------- site=GRSA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 5.78 3.91 1.61261 0.36 22.0 0.10 6.37 0.57 35.4 0.04 2.58 0.54 33.6 1990 6.16 2.91 1.95118 0.48 24.7 0.10 5.26 0.70 35.9 0.08 4.14 0.59 30.0 1991 4.42 1.64 2.08696 0.51 24.6 0.10 4.92 0.80 38.1 0.09 4.23 0.59 28.1 1992 5.38 3.17 1.68046 0.53 31.7 0.10 6.11 0.51 30.4 0.06 3.37 0.48 28.4 1993 3.93 2.19 1.51915 0.58 38.5 0.10 6.76 0.50 33.2 0.05 3.47 0.27 18.1 1994 3.39 1.88 1.24296 0.37 30.1 0.10 8.26 0.48 38.4 0.07 5.79 0.22 17.5 1995 2.64 1.35 1.28504 0.33 25.7 0.10 7.99 0.37 28.6 0.07 5.62 0.41 32.1 1996 2.84 1.69 1.19406 0.31 25.9 0.10 8.60 0.41 34.1 0.06 5.00 0.32 26.4 1997 2.83 1.22 1.46249 0.44 30.1 0.10 7.02 0.43 29.1 0.08 5.16 0.42 28.6 1998 4.13 2.24 1.88023 0.60 32.1 0.10 5.46 0.64 34.0 0.08 4.24 0.45 24.2 1999 3.64 2.02 1.47359 0.35 23.7 0.10 6.97 0.46 31.4 0.08 5.61 0.48 32.2 -------------------------------------------------- site=GRSA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 10.63 6.65 3.32419 0.90 27.0 0.18 5.29 0.95 28.5 0.11 3.32 1.20 36.0 1990 9.48 5.11 3.22643 0.79 24.4 0.18 5.45 1.01 31.2 0.14 4.28 1.12 34.7 1991 9.21 5.21 3.37319 0.79 23.3 0.18 5.21 0.99 29.4 0.06 1.88 1.36 40.2 1992 8.87 5.18 2.78914 0.87 31.3 0.18 6.30 0.89 31.8 0.09 3.20 0.76 27.4 1993 6.09 3.34 2.48668 0.81 32.7 0.18 7.07 0.81 32.7 0.10 4.04 0.58 23.5 1994 7.38 4.33 2.51483 0.81 32.1 0.18 6.99 0.85 33.8 0.11 4.48 0.57 22.7 1995 5.75 3.02 2.69441 0.79 29.3 0.18 6.53 0.71 26.3 0.11 4.04 0.91 33.8 1996 6.90 3.60 3.01230 0.78 25.8 0.18 5.84 0.70 23.3 0.11 3.62 1.25 41.4 1997 6.19 3.36 2.57314 0.92 35.8 0.18 6.83 0.81 31.4 0.09 3.68 0.57 22.3 1998 5.36 2.37 2.95199 1.00 34.0 0.18 5.96 1.12 37.8 0.12 4.21 0.53 18.1 1999 6.42 3.49 2.63679 0.75 28.3 0.18 6.67 0.95 35.8 0.11 4.11 0.66 25.1 -------------------------------------------------- site=GRSA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 18.50 12.18 5.18364 1.59 30.6 0.30 5.88 1.74 33.6 0.18 3.46 1.37 26.4 1990 25.85 19.67 4.98486 1.15 23.0 0.30 6.12 1.47 29.4 0.17 3.31 1.90 38.1 1991 19.69 13.39 5.52202 1.11 20.1 0.30 5.52 1.33 24.1 0.11 1.99 2.67 48.3 1992 9.75 5.32 3.70338 1.41 38.0 0.30 8.23 1.22 33.0 0.15 3.99 0.62 16.9 1993 11.99 7.28 4.20277 1.52 36.3 0.30 7.25 1.30 31.0 0.17 4.01 0.90 21.4 1994 34.98 27.98 5.52171 1.33 24.1 0.30 5.52 1.54 27.9 0.14 2.62 2.20 39.9 1995 9.75 5.14 4.37236 1.54 35.3 0.30 6.97 1.20 27.4 0.16 3.77 1.16 26.6 1996 14.60 8.59 5.43149 1.29 23.8 0.30 5.61 1.51 27.7 0.18 3.27 2.15 39.6 1997 13.15 7.85 4.54804 1.52 33.5 0.30 6.70 0.97 21.4 0.13 2.94 1.61 35.5 1998 10.74 5.68 5.54249 1.83 33.0 0.30 5.50 1.91 34.4 0.19 3.49 1.31 23.6 1999 16.60 11.14 4.92157 1.12 22.8 0.30 6.20 1.49 30.4 0.18 3.58 1.82 37.0 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 175 -------------------------------------------------- site=GRSM GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 8.75 3.87 4.52028 2.38 52.6 0.23 5.12 1.34 29.6 0.32 7.14 0.25 5.54 1991 7.06 2.96 3.75726 1.95 52.0 0.23 6.16 1.20 32.0 0.22 5.92 0.15 3.90 1992 8.18 4.07 3.57629 1.73 48.3 0.23 6.47 1.18 33.1 0.24 6.64 0.20 5.50 1993 7.80 3.61 3.95050 2.02 51.0 0.23 5.86 1.27 32.1 0.27 6.77 0.17 4.18 1994 7.45 3.24 3.96175 1.83 46.1 0.23 5.84 1.41 35.5 0.27 6.94 0.22 5.63 1995 7.59 3.61 3.68313 1.69 45.9 0.23 6.28 1.21 32.8 0.30 8.26 0.25 6.73 1996 10.36 4.47 4.66313 2.36 50.6 0.23 4.96 1.43 30.7 0.29 6.33 0.35 7.42 1997 8.29 3.15 4.54201 2.28 50.2 0.23 5.09 1.47 32.4 0.28 6.08 0.28 6.15 1998 9.16 4.34 4.27640 1.94 45.4 0.23 5.41 1.47 34.5 0.28 6.66 0.34 8.06 1999 10.44 5.23 4.56203 2.02 44.2 0.23 5.07 1.73 38.0 0.32 6.92 0.27 5.85 -------------------------------------------------- site=GRSM GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 15.42 4.16 9.9638 5.64 56.6 0.37 3.73 2.92 29.3 0.67 6.75 0.36 3.66 1991 14.35 5.10 8.4341 4.76 56.4 0.37 4.41 2.27 27.0 0.40 4.70 0.63 7.47 1992 16.60 5.20 9.9681 5.82 58.4 0.37 3.73 2.86 28.7 0.55 5.49 0.37 3.68 1993 16.44 5.55 10.2019 6.03 59.1 0.37 3.65 2.91 28.5 0.49 4.82 0.40 3.90 1994 14.30 4.46 8.5248 4.78 56.1 0.37 4.36 2.40 28.2 0.43 5.00 0.54 6.39 1995 17.17 7.51 8.6761 4.57 52.6 0.37 4.29 2.34 27.0 0.45 5.16 0.95 11.0 1996 14.93 5.36 8.7081 4.73 54.3 0.37 4.27 2.66 30.6 0.48 5.49 0.47 5.35 1997 14.69 4.49 8.5530 4.88 57.1 0.37 4.35 2.54 29.7 0.44 5.18 0.32 3.71 1998 15.71 3.85 10.4645 6.05 57.8 0.37 3.56 2.91 27.8 0.54 5.13 0.60 5.74 1999 16.89 4.01 10.3384 5.57 53.8 0.37 3.60 3.35 32.4 0.51 4.90 0.55 5.30 -------------------------------------------------- site=GRSM GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1990 42.42 11.92 25.2417 18.39 72.9 0.18 0.73 5.31 21.0 0.66 2.62 0.70 2.76 1991 27.79 7.02 18.6643 13.56 72.6 0.18 0.99 3.97 21.3 0.50 2.66 0.45 2.42 1992 28.04 3.78 20.2096 15.28 75.6 0.18 0.91 3.87 19.2 0.51 2.52 0.36 1.77 1993 32.00 6.46 22.1317 15.41 69.6 0.18 0.83 4.84 21.9 0.40 1.79 1.30 5.87 1994 33.55 5.68 23.1928 17.11 73.8 0.18 0.79 4.72 20.3 0.53 2.28 0.65 2.79 1995 30.34 5.87 20.4973 14.46 70.5 0.18 0.90 4.62 22.5 0.56 2.73 0.68 3.32 1996 32.54 6.53 21.6890 15.87 73.2 0.18 0.85 4.41 20.3 0.51 2.36 0.71 3.28 1997 31.08 5.10 21.2325 15.28 71.9 0.18 0.87 4.53 21.4 0.50 2.36 0.74 3.47 1998 38.80 10.92 24.2993 16.42 67.6 0.18 0.76 5.84 24.0 0.79 3.25 1.06 4.38 1999 34.62 8.56 21.1279 14.31 67.7 0.18 0.87 5.30 25.1 0.55 2.62 0.77 3.66 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 176 -------------------------------------------------- site=GUMO GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 7.19 3.84 2.75590 0.98 35.5 0.16 5.65 0.75 27.4 0.09 3.38 0.78 28.2 1992 5.59 3.38 1.98631 0.88 44.2 0.16 7.84 0.53 26.8 0.09 4.29 0.34 16.9 1993 6.46 4.09 2.20897 0.94 42.7 0.16 7.05 0.68 30.9 0.09 4.06 0.34 15.2 1994 5.76 3.47 2.00363 0.74 37.1 0.16 7.77 0.57 28.5 0.11 5.53 0.42 21.1 1995 6.93 4.12 2.66855 0.83 31.2 0.16 5.83 0.76 28.5 0.14 5.18 0.78 29.2 1996 6.12 2.52 2.87555 0.95 33.0 0.16 5.41 0.58 20.3 0.10 3.41 1.09 37.9 1997 5.80 3.11 1.95806 0.83 42.6 0.16 7.95 0.52 26.5 0.10 5.03 0.35 17.9 1998 5.61 2.97 2.23851 0.91 40.7 0.16 6.96 0.50 22.4 0.12 5.25 0.55 24.7 1999 6.96 4.19 2.33772 0.70 30.1 0.16 6.66 0.63 26.9 0.09 3.84 0.76 32.4 -------------------------------------------------- site=GUMO GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 12.96 7.57 4.07205 1.76 43.2 0.23 5.56 0.98 24.2 0.17 4.27 0.93 22.9 1992 9.11 5.17 3.42505 1.45 42.4 0.23 6.62 0.89 26.1 0.16 4.56 0.70 20.3 1993 11.21 7.22 3.68181 1.49 40.5 0.23 6.15 1.04 28.4 0.15 4.08 0.77 20.9 1994 13.05 8.13 4.21196 1.49 35.4 0.23 5.38 1.05 24.8 0.17 3.92 1.28 30.5 1995 13.70 8.85 4.36724 1.51 34.6 0.23 5.19 0.94 21.6 0.15 3.49 1.53 35.1 1996 9.61 4.10 4.81927 1.73 36.0 0.23 4.70 1.08 22.3 0.16 3.36 1.62 33.6 1997 11.42 6.17 4.04346 1.99 49.2 0.23 5.60 0.79 19.4 0.12 2.86 0.93 22.9 1998 12.94 8.19 4.38279 1.80 41.1 0.23 5.17 0.87 19.8 0.16 3.56 1.33 30.3 1999 12.47 7.50 4.20006 1.73 41.1 0.23 5.40 0.84 20.0 0.15 3.67 1.25 29.8 -------------------------------------------------- site=GUMO GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 23.61 13.61 8.9640 3.60 40.2 0.38 4.22 2.02 22.5 0.20 2.22 2.76 30.8 1992 14.33 7.18 6.5780 3.04 46.2 0.38 5.75 1.40 21.3 0.15 2.25 1.61 24.4 1993 17.67 9.82 7.0253 3.06 43.6 0.38 5.38 1.79 25.5 0.19 2.74 1.60 22.8 1994 27.66 18.53 8.3494 2.96 35.5 0.38 4.53 1.47 17.6 0.14 1.71 3.40 40.7 1995 22.71 14.50 7.5468 3.60 47.7 0.38 5.01 1.31 17.3 0.17 2.22 2.10 27.8 1996 21.19 13.39 7.0182 3.03 43.1 0.38 5.39 1.16 16.5 0.15 2.08 2.31 32.9 1997 17.39 8.52 7.9848 4.38 54.8 0.38 4.73 1.36 17.0 0.17 2.17 1.70 21.3 1998 22.79 11.98 10.1103 4.26 42.1 0.38 3.74 2.33 23.0 0.24 2.33 2.91 28.8 1999 40.97 28.29 10.3564 3.10 29.9 0.38 3.65 1.39 13.4 0.25 2.39 5.25 50.6 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 177 -------------------------------------------------- site=JARB GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 5.02 3.42 1.06895 0.33 30.4 0.04 4.07 0.40 37.8 0.04 3.41 0.26 24.3 1993 2.43 1.18 0.94396 0.29 30.7 0.04 4.61 0.40 42.0 0.04 4.15 0.18 18.6 1994 3.11 1.61 0.95571 0.31 31.9 0.04 4.55 0.38 40.0 0.03 3.53 0.19 20.0 1995 1.93 1.06 0.81625 0.21 25.8 0.04 5.33 0.35 42.4 0.05 6.42 0.16 20.0 1998 2.40 1.22 1.04168 0.29 28.3 0.04 4.18 0.42 40.1 0.05 5.25 0.23 22.2 1999 1.65 0.85 0.56144 0.17 30.7 0.04 7.75 0.14 25.2 0.03 6.16 0.17 30.2 -------------------------------------------------- site=JARB GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 8.35 5.70 2.13379 0.56 26.1 0.11 4.94 0.75 35.1 0.10 4.60 0.63 29.3 1993 6.84 4.31 2.25702 0.55 24.3 0.11 4.67 0.89 39.4 0.06 2.79 0.65 28.9 1994 7.85 5.26 2.12647 0.54 25.4 0.11 4.96 0.73 34.3 0.07 3.45 0.68 31.9 1995 4.97 2.89 1.88538 0.48 25.6 0.11 5.59 0.65 34.5 0.10 5.45 0.54 28.8 1998 6.27 4.42 1.65585 0.50 30.1 0.11 6.37 0.62 37.5 0.09 5.16 0.35 20.9 1999 8.86 5.93 2.45954 0.51 20.8 0.11 4.29 0.71 28.8 0.08 3.29 1.05 42.8 -------------------------------------------------- site=JARB GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 19.51 12.82 5.26150 1.04 19.7 0.19 3.52 1.65 31.3 0.15 2.82 2.24 42.6 1993 14.52 9.78 3.95466 0.96 24.4 0.19 4.68 1.15 29.1 0.09 2.33 1.56 39.5 1994 18.80 10.22 7.26560 0.81 11.2 0.19 2.55 3.65 50.2 0.26 3.55 2.36 32.5 1995 13.80 9.04 4.36537 0.79 18.1 0.19 4.24 1.77 40.6 0.18 4.15 1.44 32.9 1998 18.65 12.33 5.83158 0.86 14.7 0.19 3.18 2.01 34.4 0.18 3.09 2.60 44.6 1999 17.53 9.59 6.55535 0.86 13.1 0.19 2.82 2.91 44.3 0.29 4.46 2.31 35.3 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 178 -------------------------------------------------- site=JEFF GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 9.99 3.21 6.37858 2.98 46.7 0.42 6.62 2.02 31.7 0.50 7.90 0.45 7.13 1997 11.89 4.04 6.38322 3.24 50.7 0.42 6.61 1.92 30.1 0.42 6.51 0.39 6.12 1998 10.14 3.73 6.11597 2.48 40.5 0.42 6.90 2.42 39.5 0.48 7.83 0.32 5.28 1999 10.39 4.23 5.98339 2.33 38.9 0.42 7.05 2.40 40.2 0.48 8.08 0.35 5.79 -------------------------------------------------- site=JEFF GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 18.16 4.78 11.7710 5.94 50.5 0.63 5.38 3.92 33.3 0.71 6.07 0.56 4.79 1997 19.54 5.47 12.5561 5.52 44.0 0.63 5.05 4.91 39.1 0.94 7.48 0.55 4.36 1998 17.33 4.73 11.9774 5.42 45.3 0.63 5.29 4.36 36.4 0.90 7.55 0.66 5.51 1999 18.48 4.81 12.3600 4.72 38.2 0.63 5.13 5.45 44.1 1.01 8.19 0.54 4.40 -------------------------------------------------- site=JEFF GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1996 31.60 6.73 21.8013 13.79 63.3 0.40 1.85 5.89 27.0 0.98 4.49 0.74 3.38 1997 31.09 4.78 23.5744 15.08 63.9 0.40 1.71 6.37 27.0 0.97 4.11 0.76 3.22 1998 31.17 5.52 23.4352 15.15 64.6 0.40 1.72 6.13 26.2 0.96 4.10 0.79 3.36 1999 29.28 4.37 22.4529 14.33 63.8 0.40 1.79 6.08 27.1 0.88 3.94 0.76 3.39 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 179 -------------------------------------------------- site=LAVO GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 3.52 2.15 1.17253 0.25 21.2 0.04 3.46 0.48 40.8 0.05 4.54 0.35 30.0 1990 2.51 1.38 0.99912 0.20 19.8 0.04 4.07 0.56 56.1 0.05 4.80 0.15 15.2 1991 2.87 1.66 0.90967 0.17 18.4 0.04 4.47 0.55 60.9 0.04 4.44 0.11 11.8 1992 2.96 1.68 0.99131 0.24 23.8 0.04 4.10 0.47 47.6 0.06 6.40 0.18 18.0 1993 2.73 1.62 1.15349 0.31 26.5 0.04 3.52 0.52 45.0 0.06 5.30 0.23 19.7 1994 2.25 1.28 0.97099 0.24 24.6 0.04 4.18 0.44 45.2 0.06 5.93 0.20 20.1 1995 1.87 1.05 0.85025 0.23 27.3 0.04 4.78 0.33 39.1 0.05 6.39 0.19 22.4 1996 1.96 1.05 0.85138 0.18 20.9 0.04 4.77 0.43 51.0 0.05 5.96 0.15 17.4 1997 2.88 1.47 0.97643 0.24 24.6 0.04 4.16 0.46 47.5 0.05 5.51 0.18 18.2 1998 2.51 1.44 0.92886 0.16 17.4 0.04 4.37 0.57 61.2 0.05 5.69 0.11 11.3 1999 2.27 0.71 0.85601 0.19 22.5 0.04 4.75 0.42 49.3 0.07 8.41 0.13 15.1 -------------------------------------------------- site=LAVO GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 7.70 4.43 2.80556 0.59 21.2 0.13 4.77 1.42 50.6 0.18 6.38 0.48 17.1 1990 7.44 5.03 2.17804 0.43 19.7 0.13 6.15 1.16 53.4 0.13 6.11 0.32 14.6 1991 6.50 3.90 2.46201 0.45 18.2 0.13 5.44 1.45 59.0 0.17 7.10 0.25 10.2 1992 7.42 4.71 2.20546 0.53 24.1 0.13 6.07 1.03 46.8 0.14 6.57 0.36 16.4 1993 5.47 2.98 2.24360 0.58 26.0 0.13 5.97 0.99 44.1 0.12 5.54 0.41 18.4 1994 6.41 3.51 2.34693 0.48 20.4 0.13 5.71 0.97 41.4 0.12 5.27 0.64 27.2 1995 4.80 2.06 2.63481 0.57 21.6 0.13 5.08 1.09 41.4 0.16 6.24 0.68 25.7 1996 3.81 1.72 2.14027 0.47 21.8 0.13 6.26 1.02 47.5 0.13 6.26 0.39 18.3 1997 4.09 2.06 1.62747 0.38 23.1 0.13 8.23 0.82 50.2 0.10 6.23 0.20 12.2 1998 5.59 2.55 2.82018 0.58 20.7 0.13 4.75 1.66 58.9 0.17 5.88 0.28 9.79 1999 4.82 2.30 2.45696 0.49 19.8 0.13 5.45 1.27 51.8 0.17 7.10 0.39 15.9 -------------------------------------------------- site=LAVO GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 15.45 8.13 6.1435 1.45 23.5 0.38 6.23 2.82 45.9 0.43 7.03 1.06 17.3 1990 12.07 7.51 4.5099 0.90 19.9 0.38 8.49 2.40 53.3 0.35 7.72 0.48 10.6 1991 18.23 14.66 3.4859 0.55 15.8 0.38 11.0 2.04 58.4 0.25 7.10 0.27 7.71 1992 12.23 6.86 4.6490 1.18 25.4 0.38 8.24 2.35 50.6 0.31 6.74 0.42 9.01 1993 10.85 5.20 5.0412 1.12 22.2 0.38 7.60 2.54 50.3 0.26 5.06 0.75 14.9 1994 10.56 3.76 6.0264 1.25 20.7 0.38 6.36 2.58 42.8 0.31 5.18 1.50 24.9 1995 8.95 3.15 4.8371 1.21 24.9 0.38 7.92 2.16 44.6 0.31 6.42 0.78 16.1 1996 9.38 2.88 5.5198 1.20 21.7 0.38 6.94 2.82 51.1 0.36 6.58 0.76 13.7 1997 9.90 4.63 4.2051 0.96 22.8 0.38 9.11 2.02 48.0 0.25 6.00 0.59 14.1 1998 11.92 4.09 7.4110 1.28 17.2 0.38 5.17 4.02 54.3 0.54 7.28 1.19 16.0 1999 22.29 5.66 13.8885 1.22 8.76 0.38 2.76 10.09 72.6 1.34 9.67 0.86 6.17 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 180 -------------------------------------------------- site=MACA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 8.44 2.49 5.12611 2.57 50.1 0.48 9.38 1.52 29.6 0.33 6.36 0.23 4.57 1993 9.41 3.34 5.70489 3.03 53.1 0.48 8.43 1.59 27.8 0.33 5.86 0.27 4.76 1995 9.68 4.88 4.57059 2.14 46.8 0.48 10.5 1.28 28.0 0.29 6.39 0.38 8.31 1996 9.68 3.82 5.16187 2.46 47.7 0.48 9.32 1.51 29.2 0.31 5.97 0.41 7.87 1997 12.05 3.44 5.68966 2.91 51.2 0.48 8.45 1.52 26.7 0.32 5.56 0.46 8.08 1998 10.00 3.91 5.15148 2.47 48.0 0.48 9.34 1.39 27.1 0.33 6.49 0.47 9.14 1999 9.90 3.82 5.19819 2.53 48.7 0.48 9.25 1.51 29.0 0.32 6.19 0.35 6.77 -------------------------------------------------- site=MACA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 15.93 3.06 10.9581 6.72 61.4 0.65 5.92 2.73 24.9 0.52 4.76 0.33 3.02 1993 17.38 4.27 12.2469 7.47 61.0 0.65 5.30 2.89 23.6 0.54 4.41 0.70 5.71 1995 15.69 5.44 9.1162 5.16 56.6 0.65 7.12 2.38 26.1 0.55 6.07 0.38 4.13 1996 15.85 4.32 9.8293 5.73 58.3 0.65 6.60 2.58 26.2 0.50 5.12 0.37 3.74 1997 15.20 3.63 10.0646 6.17 61.3 0.65 6.45 2.39 23.7 0.48 4.77 0.38 3.75 1998 17.71 5.64 10.9850 6.58 59.9 0.65 5.91 2.75 25.0 0.55 4.98 0.46 4.22 1999 16.91 4.93 10.5624 6.16 58.3 0.65 6.14 2.72 25.8 0.50 4.75 0.53 5.00 -------------------------------------------------- site=MACA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 31.18 5.05 23.1946 16.32 70.4 0.46 1.96 4.28 18.5 0.68 2.92 1.46 6.29 1993 31.42 9.73 23.7081 17.00 71.7 0.46 1.92 3.89 16.4 0.51 2.17 1.85 7.81 1995 31.55 7.53 20.7288 14.77 71.2 0.46 2.20 4.18 20.2 0.55 2.64 0.78 3.75 1996 31.74 6.63 21.1872 15.28 72.1 0.46 2.15 4.26 20.1 0.61 2.86 0.58 2.74 1997 30.08 5.79 20.2974 14.30 70.5 0.46 2.24 4.16 20.5 0.54 2.64 0.84 4.15 1998 32.77 8.30 21.6944 14.57 67.2 0.46 2.10 5.04 23.3 0.72 3.32 0.90 4.16 1999 30.67 7.31 19.7753 13.58 68.7 0.46 2.30 4.50 22.7 0.62 3.12 0.63 3.16 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 181 -------------------------------------------------- site=MEVE GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 3.86 2.14 1.28146 0.39 30.4 0.09 6.94 0.33 25.5 0.03 2.43 0.44 34.7 1990 4.89 2.35 1.53059 0.58 37.6 0.09 5.81 0.41 26.6 0.03 2.17 0.42 27.7 1991 5.70 2.86 1.81754 0.55 30.3 0.09 4.89 0.54 29.8 0.07 3.78 0.57 31.3 1992 4.41 2.40 1.51295 0.57 37.4 0.09 5.88 0.46 30.2 0.06 3.71 0.34 22.8 1993 3.83 1.95 1.60651 0.67 41.8 0.09 5.54 0.43 26.7 0.05 3.30 0.36 22.7 1994 4.25 1.89 1.88484 0.78 41.2 0.09 4.72 0.53 27.9 0.07 3.93 0.42 22.2 1995 2.83 1.69 1.30737 0.38 29.3 0.09 6.80 0.35 27.0 0.10 7.68 0.38 29.3 1996 2.40 1.13 1.28884 0.38 29.5 0.09 6.90 0.35 27.0 0.10 7.54 0.37 29.1 1998 3.69 2.14 1.63461 0.49 29.9 0.09 5.44 0.56 34.2 0.11 6.76 0.39 23.7 1999 3.43 1.69 1.65735 0.48 28.7 0.09 5.37 0.51 30.9 0.11 6.67 0.47 28.3 -------------------------------------------------- site=MEVE GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 5.84 2.85 2.54602 0.96 37.9 0.16 6.17 0.71 28.0 0.08 3.23 0.63 24.8 1990 6.62 3.39 2.21313 0.99 44.8 0.16 7.10 0.58 26.3 0.08 3.73 0.40 18.1 1991 6.79 3.12 2.63478 1.09 41.2 0.16 5.96 0.77 29.3 0.08 2.90 0.54 20.7 1992 6.50 3.64 2.45195 1.07 43.8 0.16 6.41 0.67 27.3 0.10 4.05 0.45 18.4 1993 6.42 3.47 2.59051 0.97 37.3 0.16 6.06 0.76 29.4 0.09 3.64 0.61 23.6 1994 8.61 5.11 2.96264 1.09 36.9 0.16 5.30 0.88 29.7 0.11 3.76 0.72 24.4 1995 5.39 3.01 2.44219 0.88 36.2 0.16 6.43 0.61 25.1 0.13 5.22 0.66 27.1 1996 5.88 2.84 2.91934 0.77 26.3 0.16 5.38 0.79 27.1 0.16 5.56 1.04 35.7 1998 4.66 2.05 2.79397 0.99 35.3 0.16 5.62 1.06 37.8 0.15 5.39 0.44 15.9 1999 5.46 2.56 2.76193 0.84 30.5 0.16 5.69 0.94 34.1 0.16 5.87 0.66 23.8 -------------------------------------------------- site=MEVE GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 9.19 3.82 4.51909 2.02 44.8 0.21 4.73 1.40 31.0 0.17 3.67 0.71 15.8 1990 16.25 9.83 4.55619 1.67 36.7 0.21 4.69 1.45 31.8 0.21 4.54 1.01 22.3 1991 14.65 10.16 3.47857 1.37 39.4 0.21 6.14 0.98 28.1 0.14 4.05 0.78 22.3 1992 8.86 5.08 3.25356 1.63 50.1 0.21 6.57 0.93 28.7 0.18 5.39 0.30 9.29 1993 12.31 7.59 4.02122 1.64 40.9 0.21 5.32 1.17 29.1 0.26 6.43 0.74 18.3 1994 12.45 7.61 4.31748 1.52 35.2 0.21 4.95 1.42 32.9 0.17 3.98 0.99 22.9 1995 9.91 5.16 4.31571 1.99 46.0 0.21 4.95 1.11 25.7 0.18 4.26 0.82 19.1 1996 12.68 5.04 6.23079 1.60 25.7 0.21 3.43 2.15 34.5 0.31 5.00 1.96 31.4 1998 9.16 4.23 4.96450 1.94 39.2 0.21 4.31 1.53 30.8 0.22 4.39 1.06 21.4 1999 23.67 16.38 6.34836 1.43 22.5 0.21 3.37 1.60 25.2 0.23 3.59 2.88 45.3 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 182 -------------------------------------------------- site=MOOS GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 5.10 2.49 2.19968 0.85 38.5 0.11 5.21 0.91 41.5 0.15 7.01 0.17 7.79 1996 5.80 3.32 1.80239 0.65 35.9 0.11 6.36 0.80 44.6 0.13 7.31 0.10 5.82 1997 6.48 3.48 1.94124 0.81 41.5 0.11 5.90 0.78 40.1 0.11 5.45 0.14 7.00 1998 4.60 2.44 1.97534 0.77 39.0 0.11 5.80 0.77 39.2 0.12 6.23 0.19 9.79 1999 6.11 3.38 1.87545 0.80 42.8 0.11 6.11 0.70 37.4 0.12 6.22 0.14 7.45 -------------------------------------------------- site=MOOS GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 9.09 3.84 4.23081 2.01 47.5 0.26 6.24 1.49 35.3 0.28 6.56 0.19 4.46 1996 10.43 5.21 4.14968 2.02 48.7 0.26 6.36 1.45 35.0 0.23 5.51 0.18 4.46 1997 9.85 4.39 4.55294 2.32 51.0 0.26 5.80 1.50 33.1 0.26 5.63 0.20 4.50 1998 7.63 3.38 4.14297 1.83 44.1 0.26 6.37 1.50 36.1 0.27 6.43 0.29 6.99 1999 9.65 4.10 4.17413 1.92 46.1 0.26 6.33 1.46 34.9 0.22 5.35 0.30 7.29 -------------------------------------------------- site=MOOS GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 14.95 3.08 10.7421 6.12 57.0 0.38 3.54 3.50 32.5 0.45 4.19 0.30 2.75 1996 13.68 3.61 9.1677 5.23 57.1 0.38 4.15 2.87 31.3 0.42 4.53 0.27 2.95 1997 17.07 4.94 10.4631 5.83 55.7 0.38 3.64 3.55 34.0 0.39 3.77 0.30 2.89 1998 13.22 2.64 9.3414 5.54 59.3 0.38 4.07 2.67 28.6 0.38 4.02 0.37 3.96 1999 13.20 3.20 9.2304 5.87 63.6 0.38 4.12 2.33 25.3 0.34 3.72 0.30 3.26 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 183 -------------------------------------------------- site=MORA GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 4.15 2.38 1.32158 0.34 25.5 0.04 3.04 0.78 59.3 0.11 8.65 0.05 3.48 1992 5.32 3.46 1.34072 0.27 19.8 0.04 3.00 0.85 63.1 0.13 9.71 0.06 4.38 1993 4.69 2.83 1.56422 0.40 25.6 0.04 2.57 0.86 55.0 0.09 5.88 0.17 11.0 1994 4.35 2.70 1.07135 0.30 28.3 0.04 3.75 0.56 52.0 0.09 8.75 0.08 7.22 1995 2.87 1.82 0.82582 0.18 21.5 0.04 4.86 0.49 59.7 0.08 9.21 0.04 4.69 1996 2.48 1.82 0.97887 0.20 20.2 0.04 4.10 0.60 61.5 0.08 7.69 0.06 6.51 1997 2.76 1.35 1.01878 0.26 25.4 0.04 3.94 0.60 59.3 0.06 5.72 0.06 5.61 1998 2.82 2.18 0.82676 0.21 25.3 0.04 4.86 0.47 57.4 0.04 5.06 0.06 7.38 1999 2.62 1.61 0.96318 0.21 21.9 0.04 4.17 0.57 59.3 0.08 8.47 0.06 6.16 -------------------------------------------------- site=MORA GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 9.43 3.98 4.46160 1.38 31.0 0.15 3.44 2.33 52.3 0.39 8.71 0.20 4.57 1992 8.35 3.17 4.40151 1.06 24.2 0.15 3.49 2.56 58.1 0.40 9.19 0.22 5.07 1993 8.17 3.03 4.47427 1.24 27.8 0.15 3.43 2.50 55.9 0.39 8.70 0.19 4.18 1994 7.88 3.37 3.76612 1.08 28.7 0.15 4.08 2.00 53.2 0.35 9.41 0.17 4.60 1995 6.33 2.69 3.06521 0.97 31.5 0.15 5.01 1.55 50.6 0.27 8.96 0.12 3.93 1996 6.81 2.59 3.44627 1.16 33.8 0.15 4.46 1.64 47.7 0.29 8.51 0.19 5.54 1997 6.73 2.97 3.07924 0.88 28.7 0.15 4.99 1.67 54.2 0.25 8.13 0.12 3.90 1998 6.18 2.47 3.60722 1.22 33.7 0.15 4.26 1.75 48.4 0.31 8.60 0.18 5.01 1999 6.41 2.83 3.35158 1.01 30.1 0.15 4.59 1.78 53.2 0.26 7.68 0.15 4.46 -------------------------------------------------- site=MORA GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 18.19 6.79 9.4573 3.19 33.7 0.35 3.72 4.79 50.7 0.79 8.37 0.34 3.56 1992 16.15 3.61 10.1475 3.09 30.4 0.35 3.47 5.32 52.4 0.89 8.77 0.50 4.95 1993 13.82 3.86 8.6917 3.08 35.4 0.35 4.05 4.28 49.2 0.65 7.43 0.34 3.89 1994 16.13 5.51 8.7987 3.02 34.3 0.35 4.00 4.30 48.9 0.66 7.49 0.47 5.29 1995 13.27 4.63 7.5498 2.46 32.6 0.35 4.66 3.70 49.0 0.62 8.26 0.42 5.52 1996 13.36 3.31 8.6521 2.18 25.2 0.35 4.07 4.86 56.2 0.77 8.95 0.48 5.57 1997 13.51 4.22 7.5142 2.47 32.9 0.35 4.68 3.77 50.1 0.51 6.83 0.41 5.47 1998 13.73 4.18 9.4550 3.30 34.9 0.35 3.72 4.27 45.1 0.71 7.49 0.83 8.78 1999 12.65 3.20 8.6506 2.98 34.5 0.35 4.07 4.28 49.5 0.62 7.18 0.42 4.80 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 184 -------------------------------------------------- site=MOZI GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 3.66 2.54 1.00892 0.39 38.6 0.07 7.20 0.27 27.2 0.06 5.65 0.22 21.4 1996 3.46 2.12 0.94707 0.40 42.5 0.07 7.66 0.26 27.1 0.06 6.09 0.16 16.6 1997 2.90 2.22 0.78350 0.35 44.2 0.07 9.27 0.21 27.2 0.05 6.42 0.10 12.9 1998 2.76 1.70 1.21913 0.50 40.8 0.07 5.95 0.42 34.2 0.07 5.41 0.17 13.7 1999 3.09 2.08 1.03307 0.41 39.3 0.07 7.03 0.34 33.3 0.06 5.85 0.15 14.5 -------------------------------------------------- site=MOZI GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 6.01 3.99 2.00261 0.75 37.6 0.15 7.47 0.52 26.0 0.09 4.65 0.49 24.4 1996 6.76 4.17 2.44690 0.77 31.3 0.15 6.11 0.78 32.0 0.12 4.98 0.63 25.6 1997 5.00 2.65 2.11259 0.95 45.0 0.15 7.08 0.54 25.5 0.08 3.73 0.40 18.8 1998 5.79 3.31 2.64562 0.95 36.0 0.15 5.65 0.94 35.5 0.13 4.94 0.48 18.0 1999 5.76 3.32 2.32400 0.75 32.4 0.15 6.44 0.76 32.8 0.11 4.87 0.54 23.4 -------------------------------------------------- site=MOZI GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1995 10.23 5.62 4.08857 1.36 33.3 0.19 4.67 1.17 28.5 0.16 3.94 1.21 29.6 1996 12.75 7.12 4.76965 1.28 26.9 0.19 4.01 1.91 40.1 0.23 4.87 1.15 24.2 1997 8.66 4.51 3.52149 1.46 41.5 0.19 5.43 1.04 29.6 0.12 3.42 0.71 20.1 1998 10.17 5.63 4.67164 1.57 33.6 0.19 4.09 1.74 37.3 0.16 3.49 1.00 21.5 1999 12.65 7.73 4.58887 0.98 21.3 0.19 4.16 1.29 28.1 0.15 3.26 1.98 43.2 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 185 -------------------------------------------------- site=OKEF GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 9.83 3.88 4.94293 2.29 46.3 0.34 6.85 1.61 32.6 0.26 5.32 0.44 8.96 1993 10.28 4.07 5.27301 2.64 50.1 0.34 6.42 1.68 31.8 0.22 4.27 0.39 7.33 1994 11.89 5.95 4.89843 1.86 37.9 0.34 6.92 1.56 31.9 0.23 4.78 0.91 18.5 1995 10.93 5.89 3.91136 1.70 43.5 0.34 8.66 1.32 33.7 0.27 6.96 0.28 7.13 1996 13.32 7.58 4.84593 2.20 45.3 0.34 6.99 1.48 30.5 0.28 5.77 0.55 11.4 1997 14.16 8.64 4.53349 1.90 41.9 0.34 7.47 1.37 30.2 0.25 5.62 0.67 14.8 1998 13.06 6.40 5.60049 2.64 47.1 0.34 6.05 1.95 34.9 0.30 5.42 0.37 6.55 1999 10.24 4.82 5.02081 1.72 34.3 0.34 6.75 1.83 36.4 0.29 5.70 0.85 16.9 -------------------------------------------------- site=OKEF GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 16.16 5.45 9.25043 5.31 57.4 0.40 4.37 2.63 28.4 0.46 4.94 0.45 4.86 1993 17.78 7.14 9.77938 5.16 52.8 0.40 4.13 2.82 28.8 0.40 4.08 1.00 10.2 1994 17.06 6.98 9.13689 4.30 47.1 0.40 4.42 2.72 29.8 0.52 5.69 1.19 13.0 1995 16.93 6.96 8.70579 4.31 49.5 0.40 4.64 2.77 31.8 0.58 6.67 0.64 7.35 1996 21.36 11.35 8.32599 4.46 53.6 0.40 4.86 2.49 30.0 0.42 5.01 0.55 6.59 1997 18.93 9.19 8.40592 4.33 51.5 0.40 4.81 2.18 26.0 0.37 4.43 1.11 13.3 1998 16.36 6.95 8.99969 4.34 48.2 0.40 4.49 2.65 29.4 0.48 5.32 1.13 12.6 1999 17.71 6.76 9.45430 4.90 51.8 0.40 4.28 3.12 33.0 0.47 4.94 0.57 6.00 -------------------------------------------------- site=OKEF GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1992 26.73 5.23 19.4216 10.72 55.2 0.38 1.95 5.06 26.1 0.76 3.90 2.50 12.9 1993 30.36 10.42 18.4540 11.66 63.2 0.38 2.06 4.13 22.4 0.50 2.69 1.79 9.68 1994 27.80 10.41 15.7475 8.68 55.1 0.38 2.41 4.17 26.5 0.69 4.35 1.83 11.6 1995 26.88 9.82 16.0712 11.17 69.5 0.38 2.36 3.39 21.1 0.49 3.04 0.65 4.04 1996 25.04 8.93 14.7596 9.23 62.5 0.38 2.57 3.97 26.9 0.61 4.13 0.57 3.86 1997 30.82 13.01 15.4206 9.92 64.3 0.38 2.46 3.90 25.3 0.55 3.54 0.68 4.42 1998 26.46 8.61 15.9164 9.81 61.7 0.38 2.38 4.34 27.3 0.65 4.09 0.73 4.58 1999 26.68 7.17 17.6146 10.61 60.2 0.38 2.15 5.26 29.9 0.64 3.61 0.73 4.16 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 186 -------------------------------------------------- site=PEFO GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 6.49 3.15 2.78821 0.75 26.9 0.12 4.32 0.91 32.6 0.18 6.52 0.83 29.7 1992 4.95 2.10 2.60952 0.80 30.7 0.12 4.61 0.92 35.1 0.14 5.43 0.63 24.1 1993 4.51 2.36 1.89888 0.68 36.1 0.12 6.34 0.51 26.8 0.08 4.00 0.51 26.8 1994 4.63 2.18 1.78290 0.60 33.5 0.12 6.75 0.55 31.1 0.11 5.97 0.40 22.7 1995 4.42 2.34 1.92225 0.54 28.0 0.12 6.26 0.51 26.6 0.14 7.43 0.61 31.7 1996 3.41 1.85 1.67082 0.51 30.3 0.12 7.20 0.55 32.7 0.13 7.71 0.37 22.1 1997 4.98 2.46 2.14087 0.58 27.1 0.12 5.62 0.70 32.5 0.15 6.84 0.60 27.9 1998 4.95 2.76 2.09419 0.66 31.4 0.12 5.75 0.63 30.1 0.12 5.83 0.56 26.8 1999 3.90 1.69 2.08123 0.63 30.5 0.12 5.78 0.65 31.4 0.15 7.05 0.53 25.3 -------------------------------------------------- site=PEFO GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 8.99 4.53 4.00870 1.36 33.8 0.19 4.84 1.15 28.6 0.35 8.72 0.96 24.0 1992 7.77 3.15 3.85819 1.36 35.3 0.19 5.03 1.22 31.7 0.33 8.50 0.75 19.5 1993 7.49 3.41 3.42214 1.20 35.2 0.19 5.67 1.12 32.6 0.25 7.19 0.66 19.3 1994 6.69 2.86 3.26432 1.11 34.0 0.19 5.94 1.03 31.5 0.31 9.51 0.62 19.0 1995 6.66 3.15 2.97770 0.94 31.5 0.19 6.51 0.91 30.6 0.25 8.44 0.69 23.0 1996 8.60 4.85 3.26658 0.84 25.7 0.19 5.94 0.90 27.7 0.20 6.23 1.12 34.4 1997 7.41 3.42 3.49988 1.21 34.7 0.19 5.54 1.00 28.7 0.23 6.56 0.86 24.5 1998 8.15 4.86 3.11895 0.93 29.9 0.19 6.22 1.04 33.4 0.25 7.92 0.70 22.5 1999 6.73 3.23 3.41392 1.01 29.6 0.19 5.68 1.13 33.1 0.22 6.53 0.86 25.1 -------------------------------------------------- site=PEFO GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1991 13.78 7.91 5.32028 1.70 32.0 0.29 5.42 1.74 32.8 0.48 8.94 1.11 20.9 1992 12.34 7.18 4.18012 1.97 47.2 0.29 6.90 1.16 27.7 0.35 8.43 0.41 9.74 1993 8.76 3.71 4.78882 1.79 37.3 0.29 6.02 1.68 35.0 0.39 8.18 0.65 13.5 1994 10.78 6.09 4.50177 1.68 37.2 0.29 6.41 1.38 30.6 0.34 7.59 0.82 18.1 1995 9.53 3.78 5.35214 2.21 41.2 0.29 5.39 1.70 31.7 0.35 6.49 0.81 15.2 1996 12.54 7.07 5.10396 1.99 39.1 0.29 5.65 1.46 28.7 0.27 5.29 1.09 21.3 1997 12.86 7.15 5.12226 1.82 35.5 0.29 5.63 1.31 25.5 0.29 5.73 1.41 27.6 1998 10.06 4.75 5.89068 2.33 39.5 0.29 4.90 2.08 35.3 0.36 6.14 0.83 14.1 1999 14.84 8.52 5.88094 1.40 23.7 0.29 4.90 2.19 37.2 0.37 6.36 1.63 27.7 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 187 -------------------------------------------------- site=PINN GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 7.77 4.75 2.29738 0.74 32.1 0.37 16.2 0.82 35.5 0.17 7.21 0.21 9.01 1990 9.12 4.69 2.21944 0.68 30.5 0.37 16.8 0.81 36.6 0.14 6.27 0.22 9.88 1991 8.96 5.68 2.12265 0.74 34.7 0.37 17.5 0.74 34.7 0.10 4.88 0.17 8.16 1992 8.22 5.14 2.03162 0.67 33.0 0.37 18.3 0.69 33.9 0.12 5.92 0.18 8.91 1993 7.12 4.70 1.79554 0.65 36.1 0.37 20.7 0.53 29.6 0.09 4.75 0.16 8.78 1994 7.74 4.58 2.25339 0.67 29.7 0.37 16.5 0.84 37.3 0.17 7.63 0.20 8.89 1995 6.68 4.72 1.66301 0.46 27.6 0.37 22.4 0.57 34.3 0.13 7.58 0.14 8.21 1996 5.82 3.65 1.70360 0.42 24.6 0.37 21.8 0.72 42.3 0.10 5.67 0.09 5.57 1997 6.89 3.82 2.15818 0.59 27.5 0.37 17.2 0.80 37.1 0.16 7.45 0.23 10.7 1999 6.59 3.75 1.97998 0.63 31.6 0.37 18.8 0.69 34.6 0.14 7.00 0.16 7.97 -------------------------------------------------- site=PINN GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 15.22 8.52 5.27436 1.53 29.0 0.89 16.9 2.03 38.4 0.42 8.02 0.41 7.73 1990 16.60 8.91 4.90986 1.26 25.7 0.89 18.1 1.88 38.2 0.44 8.96 0.44 8.98 1991 15.97 8.81 5.12741 1.63 31.7 0.89 17.3 1.96 38.3 0.35 6.80 0.30 5.84 1992 16.84 11.20 4.70093 1.51 32.2 0.89 18.9 1.55 33.0 0.32 6.89 0.42 9.01 1993 14.09 7.65 5.00641 1.47 29.3 0.89 17.8 1.86 37.2 0.34 6.70 0.45 9.00 1994 10.98 6.37 4.22314 0.94 22.2 0.89 21.0 1.72 40.6 0.38 8.95 0.30 7.20 1995 11.20 6.13 4.80356 1.53 31.8 0.89 18.5 1.65 34.4 0.35 7.38 0.38 7.89 1996 12.64 7.47 4.74030 1.30 27.5 0.89 18.8 1.70 35.8 0.36 7.54 0.49 10.4 1997 12.33 7.27 4.26258 1.15 26.9 0.89 20.9 1.52 35.7 0.27 6.41 0.43 10.1 1999 11.39 6.49 4.35065 1.09 25.1 0.89 20.4 1.68 38.5 0.32 7.43 0.37 8.49 -------------------------------------------------- site=PINN GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 23.17 11.46 9.69541 2.51 25.9 1.45 14.9 4.18 43.1 0.97 10.1 0.58 6.00 1990 24.21 12.35 9.26946 2.60 28.1 1.45 15.6 3.79 40.8 0.83 8.96 0.60 6.51 1991 24.78 14.48 8.76748 2.30 26.2 1.45 16.5 3.59 40.9 0.72 8.16 0.72 8.22 1992 27.23 16.55 8.74083 2.51 28.7 1.45 16.6 3.06 35.0 0.60 6.92 1.12 12.8 1993 20.84 11.25 8.48571 2.13 25.1 1.45 17.1 3.46 40.7 0.66 7.73 0.79 9.35 1994 18.47 10.23 7.52836 2.32 30.8 1.45 19.2 2.69 35.7 0.52 6.96 0.55 7.29 1995 22.99 13.27 8.20944 2.28 27.8 1.45 17.6 3.02 36.7 0.72 8.82 0.74 8.99 1996 17.87 9.17 8.19871 1.95 23.8 1.45 17.6 3.38 41.2 0.61 7.46 0.81 9.87 1997 18.41 9.51 7.83961 1.86 23.8 1.45 18.5 3.15 40.2 0.61 7.83 0.76 9.73 1999 22.21 11.01 9.90104 2.57 26.0 1.45 14.6 4.20 42.4 0.69 7.00 0.99 9.98 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 188 -------------------------------------------------- site=PORE GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 9.31 6.95 1.53796 0.63 41.1 0.20 13.3 0.56 36.4 0.07 4.71 0.07 4.49 1990 12.97 8.77 1.37402 0.74 53.6 0.20 14.9 0.32 23.1 0.03 2.27 0.08 6.13 1991 11.20 7.22 1.48926 0.81 54.1 0.20 13.7 0.35 23.3 0.04 2.41 0.10 6.42 1992 8.97 6.00 1.56512 0.72 46.0 0.20 13.0 0.47 30.1 0.08 5.14 0.09 5.79 1993 10.74 7.51 1.66651 0.91 54.9 0.20 12.3 0.41 24.7 0.04 2.45 0.10 5.74 1994 8.48 4.79 1.45227 0.72 49.3 0.20 14.1 0.37 25.7 0.06 3.87 0.10 7.01 1995 5.98 3.43 1.50750 0.63 42.0 0.20 13.5 0.50 32.9 0.09 5.78 0.09 5.81 1996 6.78 3.71 1.54782 0.68 44.1 0.20 13.2 0.50 32.5 0.07 4.40 0.09 5.84 1998 9.85 6.02 1.68071 0.76 45.2 0.20 12.1 0.55 32.8 0.04 2.39 0.13 7.46 1999 8.60 4.77 1.74013 0.93 53.2 0.20 11.7 0.46 26.7 0.04 2.52 0.10 5.86 -------------------------------------------------- site=PORE GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 20.81 13.51 3.81633 1.86 48.8 0.49 12.9 1.21 31.6 0.11 2.77 0.15 3.93 1990 22.77 15.74 3.28743 1.65 50.3 0.49 15.0 0.91 27.8 0.11 3.25 0.12 3.65 1991 17.76 11.32 3.44035 1.65 48.0 0.49 14.3 1.05 30.7 0.11 3.11 0.13 3.88 1992 14.31 8.57 3.49790 1.71 48.8 0.49 14.1 0.99 28.4 0.14 3.98 0.17 4.78 1993 21.11 15.41 3.08046 1.45 47.0 0.49 16.0 0.86 27.9 0.08 2.72 0.20 6.46 1994 16.07 8.68 3.01761 1.60 53.1 0.49 16.3 0.67 22.3 0.08 2.69 0.17 5.64 1995 14.56 8.69 2.94952 1.48 50.1 0.49 16.7 0.65 22.2 0.09 3.17 0.23 7.87 1996 15.01 9.28 2.96513 1.28 43.1 0.49 16.6 0.88 29.6 0.09 3.11 0.23 7.65 1998 14.62 8.89 3.00637 1.49 49.4 0.49 16.4 0.77 25.6 0.03 1.10 0.23 7.55 1999 17.22 10.94 3.06091 1.31 42.7 0.49 16.1 0.97 31.6 0.10 3.33 0.19 6.31 -------------------------------------------------- site=PORE GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 30.77 15.17 11.3829 2.03 17.8 2.36 20.7 5.47 48.0 1.16 10.2 0.38 3.30 1990 26.22 14.91 8.7344 2.40 27.5 2.36 27.0 3.17 36.3 0.54 6.23 0.26 3.00 1991 31.34 19.13 8.7110 2.45 28.1 2.36 27.1 3.10 35.6 0.53 6.10 0.27 3.13 1992 25.39 13.53 9.1636 3.32 36.2 2.36 25.7 2.76 30.1 0.49 5.31 0.24 2.60 1993 33.88 20.00 9.0455 2.42 26.8 2.36 26.1 3.37 37.2 0.46 5.11 0.43 4.80 1994 20.44 7.06 8.8546 2.47 27.9 2.36 26.6 3.12 35.3 0.61 6.93 0.29 3.27 1995 23.92 11.37 7.9989 3.10 38.8 2.36 29.5 1.90 23.7 0.35 4.43 0.29 3.62 1996 25.36 12.84 8.2007 3.04 37.1 2.36 28.7 2.10 25.6 0.32 3.87 0.39 4.71 1998 22.90 11.44 8.2854 2.59 31.3 2.36 28.5 2.58 31.1 0.31 3.73 0.45 5.46 1999 24.32 9.47 11.1359 3.20 28.8 2.36 21.2 4.55 40.9 0.51 4.55 0.52 4.63 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 189 -------------------------------------------------- site=REDW GROUP=10 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 5.87 3.76 1.10118 0.30 26.9 0.08 7.37 0.59 53.3 0.09 7.87 0.05 4.55 1990 5.82 3.25 1.08558 0.30 27.5 0.08 7.48 0.62 56.7 0.06 5.14 0.04 3.26 1991 5.87 3.59 1.12396 0.28 25.0 0.08 7.22 0.65 57.4 0.05 4.43 0.07 5.89 1992 6.28 4.68 1.01862 0.28 27.2 0.08 7.97 0.55 54.1 0.07 6.64 0.04 4.08 1993 5.36 3.61 1.00065 0.30 30.3 0.08 8.11 0.49 49.1 0.06 6.46 0.06 6.04 1994 5.12 3.75 0.88099 0.23 26.6 0.08 9.21 0.42 48.0 0.10 11.1 0.05 5.11 1995 5.71 3.82 0.96755 0.28 28.8 0.08 8.39 0.48 49.2 0.08 8.14 0.05 5.42 1996 3.85 2.21 0.77563 0.26 33.7 0.08 10.5 0.34 43.9 0.03 3.54 0.07 8.44 1997 5.56 3.12 0.97951 0.26 26.4 0.08 8.29 0.52 53.1 0.06 5.76 0.06 6.40 1998 5.47 3.64 0.75017 0.20 26.1 0.08 10.8 0.36 47.8 0.04 5.92 0.07 9.38 1999 5.67 3.54 0.90165 0.29 31.8 0.08 9.00 0.40 44.1 0.06 6.61 0.08 8.43 -------------------------------------------------- site=REDW GROUP=50 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 10.21 6.17 2.74755 1.01 36.7 0.24 8.82 1.22 44.3 0.18 6.51 0.10 3.64 1990 10.72 6.05 2.92846 0.93 31.6 0.24 8.28 1.52 51.8 0.16 5.49 0.08 2.85 1991 10.34 6.18 2.90350 0.89 30.8 0.24 8.35 1.46 50.3 0.14 4.90 0.16 5.60 1992 9.65 4.75 2.67374 0.88 32.8 0.24 9.06 1.25 46.7 0.16 5.93 0.15 5.45 1993 8.49 4.58 2.47790 0.72 29.1 0.24 9.78 1.23 49.8 0.12 4.79 0.16 6.48 1994 9.14 4.99 2.53060 0.74 29.3 0.24 9.58 1.30 51.4 0.13 5.03 0.12 4.68 1995 10.72 6.97 2.27349 0.83 36.5 0.24 10.7 0.94 41.5 0.11 4.73 0.15 6.56 1996 7.44 3.98 2.22502 0.90 40.3 0.24 10.9 0.89 39.8 0.07 2.93 0.13 6.06 1997 10.34 5.78 2.08292 0.88 42.4 0.24 11.6 0.79 37.8 0.05 2.58 0.12 5.58 1998 6.87 3.93 1.75537 0.68 38.6 0.24 13.8 0.66 37.5 0.06 3.25 0.12 6.88 1999 8.22 4.49 1.96215 0.81 41.2 0.24 12.4 0.71 36.3 0.08 3.97 0.12 6.12 -------------------------------------------------- site=REDW GROUP=90 -------------------------------------------------- YEAR TM CM RCFM SO4 F_SO4 NO3 F_NO3 OMC F_OMC LAC F_LAC SOIL F_SOIL 1989 17.32 8.66 6.36053 2.34 36.8 0.61 9.62 2.84 44.6 0.29 4.59 0.28 4.38 1990 21.97 10.79 6.24363 2.50 40.0 0.61 9.80 2.65 42.4 0.24 3.84 0.25 3.98 1991 17.86 7.58 6.27956 2.15 34.3 0.61 9.74 2.91 46.4 0.26 4.16 0.34 5.43 1992 19.16 8.48 6.81484 2.37 34.8 0.61 8.98 3.26 47.9 0.31 4.49 0.26 3.89 1993 15.74 6.65 6.00199 1.78 29.7 0.61 10.2 3.02 50.3 0.23 3.84 0.36 5.98 1994 13.84 6.81 4.61611 1.83 39.6 0.61 13.2 1.78 38.6 0.17 3.76 0.22 4.85 1995 16.24 7.66 5.93800 2.12 35.7 0.61 10.3 2.70 45.5 0.24 3.98 0.27 4.57 1996 14.85 6.48 4.90163 2.13 43.5 0.61 12.5 1.67 34.1 0.14 2.96 0.34 7.00 1997 17.66 9.41 6.24839 1.97 31.6 0.61 9.79 3.23 51.6 0.21 3.36 0.23 3.62 1998 12.27 5.82 4.04086 1.87 46.4 0.61 15.1 1.14 28.3 0.12 2.91 0.30 7.33 1999 22.16 8.94 9.77059 1.53 15.7 0.61 6.26 6.75 69.1 0.54 5.54 0.33 3.38 ANNUAL TRENDS - AMBIENT MASS 09:37 Thursday, March 14, 2002 190 -------------------------------------------------- site=ROMA GROUP=10 --------------------------------------------